Theoretical study of regioselectivity in the synthesis of spiro [pyrrolidine-2,3'-oxindole] compounds by [3+2] cycloaddition
文献类型：期刊论文
| 作者 | Chen, Gang; Yang, Jing ; Gao, Suo; Zhang, Yu; Hao, Xiaojiang
|
| 刊名 | RESEARCH ON CHEMICAL INTERMEDIATES
 |
| 出版日期 | 2015-07-01 |
| 卷号 | 41期号:7页码:4987-4996 |
| 关键词 | Regioselectivity Theoretical Spiro-oxindole [3+2] Cycloaddition |
| 英文摘要 | Study of the structures of a series of spiro [pyrrolidine-2,3'-oxindole] derivatives synthesized by [3+2] cycloaddition reaction of isatin, alpha-amino acids, and beta-substituted phenylethylenes revealed the regioselectivity of the reaction was completely novel. The reaction mechanism for [3+2] cycloaddition of oxindole azomethine ylide and the beta-substituted phenylethylenes was calculated by use of density functional theory with the B3LYP functional and different basis sets. The results show that the regioselectivity of this [3+2] cycloaddition reaction is kinetically controlled, which agrees with experimental results. |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | 1,3-DIPOLAR CYCLOADDITION ; DERIVATIVES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000356608700072 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/24975]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Chen, Gang,Yang, Jing,Gao, Suo,et al. Theoretical study of regioselectivity in the synthesis of spiro [pyrrolidine-2,3'-oxindole] compounds by [3+2] cycloaddition[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2015,41(7):4987-4996. |
| APA | Chen, Gang,Yang, Jing,Gao, Suo,Zhang, Yu,&Hao, Xiaojiang.(2015).Theoretical study of regioselectivity in the synthesis of spiro [pyrrolidine-2,3'-oxindole] compounds by [3+2] cycloaddition.RESEARCH ON CHEMICAL INTERMEDIATES,41(7),4987-4996. |
| MLA | Chen, Gang,et al."Theoretical study of regioselectivity in the synthesis of spiro [pyrrolidine-2,3'-oxindole] compounds by [3+2] cycloaddition".RESEARCH ON CHEMICAL INTERMEDIATES 41.7(2015):4987-4996. |
入库方式： OAI收割
来源：昆明植物研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。