Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions
文献类型：期刊论文
| 作者 | Lv, Xiaoxia1; Li, Liangjun1 ; Sun, Xiaoming2; Zhang, Hongyu2; Cai, Jinjun1; Wang, Chao1; Tang, Sifu1; Zhao, Xuebo1
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| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2014-03-01 |
| 卷号 | 9期号:3页码:901-907 |
| 关键词 | coordination polymers diphosphonate ligand hysteresis sorption pi interactions polymers |
| 英文摘要 | The microporous coordination polymer [Co(H2L)(bipy)(0.5)]2H(2)O (1, bipy=4,4-bipyridine) was synthesized on the basis of the V-shaped flexible diphosphonate ligand (2,4,6-trimethyl-1,3-phenylene)bis(methylene)diphosphonic acid (H4L) and the auxiliary bipy ligand under hydrothermal conditions. The structure of this compound was characterized by single-crystal X-ray diffraction. By joining the diphosphonate ligands and bipy through tetrahedral [CoO3N] clusters, a 2D square grid layered network was formed. Further stacking of these layers on the basis of - interactions resulted in a pseudo-3D microporous network with 1D channels running through the a axis. Gas sorption studies for CO2, H-2, CH4, N-2, and O-2 on this coordination polymer were performed, and the results revealed interesting dynamic and hysteresis sorption behavior toward H-2 at low temperature. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | METAL-ORGANIC FRAMEWORKS ; ZEOLITIC IMIDAZOLATE FRAMEWORKS ; BUILDING-BLOCKS ; ADSORPTION PROPERTIES ; SELECTIVE ADSORPTION ; MAGNETIC-PROPERTIES ; BRIDGING-LIGAND ; HYDROGEN ; CO2 ; TRANSFORMATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000331611900030 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6154]  |
| 专题 | 青岛生物能源与过程研究所_储氢及新型纳孔材料团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Lab Hydrogen Storage & Novel Nanoporous Mat, Qingdao 266101, Peoples R China 2.China Univ Petr, Sch Chem Engn, State Key Lab Heavy Oil, Qingdao 266555, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Xiaoxia,Li, Liangjun,Sun, Xiaoming,et al. Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions[J]. CHEMISTRY-AN ASIAN JOURNAL,2014,9(3):901-907. |
| APA | Lv, Xiaoxia.,Li, Liangjun.,Sun, Xiaoming.,Zhang, Hongyu.,Cai, Jinjun.,...&Zhao, Xuebo.(2014).Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions.CHEMISTRY-AN ASIAN JOURNAL,9(3),901-907. |
| MLA | Lv, Xiaoxia,et al."Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions".CHEMISTRY-AN ASIAN JOURNAL 9.3(2014):901-907. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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