Structure tuning of metal phosphonates: Syntheses, structures and characterizations of two new lead (II) trisphosphonates
文献类型：期刊论文
| 作者 | Tang, Si-Fu; Lv, Xiao-Xia; Li, Liang-Jun; Wang, Chao; Zhao, Xue-Bo |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2014 |
| 卷号 | 39页码:51-55 |
| 关键词 | Phosphonates Lead Crystal structure Characterization |
| 英文摘要 | Two lead (II) trisphosphonates, [Pb-3(H3L1)(2)(H2O)] (1) and [Pb-5(HL2)(H3L2)(H4L2)(H2O)(2)][(H2O)(2)] (2), have been synthesized from two trisphosphonate ligands and characterized by EA, IR, UV-vis, TGA, powder and single-crystal X-ray diffraction methods. The single-crystal X-ray diffraction analyses reveal that they both feature three-dimensional framework structures. The lead (II)ions are mainly five-coordinated, forming square pyramid coordination geometry. Although the two trisphosphonate ligands are very similar, different coordination modes and conformations are observed for them, suggesting that attachment of methyl groups to the central benzene ring has a major effect on the structure formation. They both absorb below 325 nm and are thermally robust. (C) 2013 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ORGANIC FRAMEWORKS ; CRYSTAL-STRUCTURES ; DIPHOSPHONATES ; LIGANDS ; TETRANUCLEAR ; LINKERS ; CLUSTER ; FILMS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000330157700012 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6227]  |
| 专题 | 青岛生物能源与过程研究所_储氢及新型纳孔材料团队 |
| 作者单位 | Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Si-Fu,Lv, Xiao-Xia,Li, Liang-Jun,et al. Structure tuning of metal phosphonates: Syntheses, structures and characterizations of two new lead (II) trisphosphonates[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2014,39:51-55. |
| APA | Tang, Si-Fu,Lv, Xiao-Xia,Li, Liang-Jun,Wang, Chao,&Zhao, Xue-Bo.(2014).Structure tuning of metal phosphonates: Syntheses, structures and characterizations of two new lead (II) trisphosphonates.INORGANIC CHEMISTRY COMMUNICATIONS,39,51-55. |
| MLA | Tang, Si-Fu,et al."Structure tuning of metal phosphonates: Syntheses, structures and characterizations of two new lead (II) trisphosphonates".INORGANIC CHEMISTRY COMMUNICATIONS 39(2014):51-55. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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