中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of L-lactide

文献类型:期刊论文

作者Xu, Xianrui1,2; Pan, Xiaobo1; Tang, Sifu1; Lv, Xiaoxia1,2; Li, Liangjun1,2; Wu, Jincai3; Zhao, Xuebo1
刊名INORGANIC CHEMISTRY COMMUNICATIONS
出版日期2013-03-01
卷号29期号:1页码:89-93
关键词Sodium complexes Catalyst Ring opening polymerization Polydispersity indexes
英文摘要

Two sodium complexes, [(mu(3)-MDBP)Na-2(THF)(2)](2)[(mu(3)-OCH2CH2OCH3)Na](2) (1) and [(mu(1)-MDBP)Na(mu(2)-H2O)(THF)](2)(THF)(2) (2) have been synthesized and structurally characterized. Experimental results show that complex 1 initiates efficiently the ring opening polymerization of L-lactide in a controlled fashion, yielding polymers with narrow polydispersity indexes in a wide range of monomer-to-initiator ratios. (c) 2013 Elsevier B.V. All rights reserved.

WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]CYCLIC ESTERS ; EPSILON-CAPROLACTONE ; RAC-LACTIDE ; MAGNESIUM COMPLEXES ; KETIMINATE COMPLEXES ; ALUMINUM COMPLEXES ; SELECTIVE BINDING ; METAL-COMPLEXES ; ZINC-COMPLEXES ; INITIATORS
收录类别SCI
语种英语
WOS记录号WOS:000316532300022
源URL[http://ir.qibebt.ac.cn/handle/337004/6027]  
专题青岛生物能源与过程研究所_多相催化转化团队
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Beijing 100864, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Xu, Xianrui,Pan, Xiaobo,Tang, Sifu,et al. Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of L-lactide[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2013,29(1):89-93.
APA Xu, Xianrui.,Pan, Xiaobo.,Tang, Sifu.,Lv, Xiaoxia.,Li, Liangjun.,...&Zhao, Xuebo.(2013).Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of L-lactide.INORGANIC CHEMISTRY COMMUNICATIONS,29(1),89-93.
MLA Xu, Xianrui,et al."Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of L-lactide".INORGANIC CHEMISTRY COMMUNICATIONS 29.1(2013):89-93.

入库方式: OAI收割

来源:青岛生物能源与过程研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。