Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts
文献类型：期刊论文
| 作者 | Zhou, Ming-Dong1,2; Liu, Mei-Ju1; Huang, Liang-Liang1; Zhang, Jian1; Wang, Jing-Yun2; Li, Xue-Bing3 ; Kuehn, Fritz E.2; Zang, Shu-Liang1
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| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:2页码:1186-1193 |
| 英文摘要 | Mo8O264- based organic polyoxomolybdate salts of general formula [Hmim](4)Mo8O26 (Hmim = 1-hexyl-3-methylimidazolium), [Dhmim](4)Mo8O26 (Dhmim = 1,2-dimethyl-3-hexylimidazolium) and [Hpy](4)Mo8O26 center dot H2O (Hpy = 1-hexylpyridinium) have been prepared and characterized. These compounds were applied as catalysts for olefin epoxidation using hydrogen peroxide (H2O2) as oxidant in CH3CN. The polyoxomolybdate salts exhibit excellent catalytic performance and are also self-separating, a great advantage for catalyst recycling. The catalysts can be reused for at least 10 runs without significant loss of activity. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | PHASE-TRANSFER CATALYSIS ; IONIC LIQUIDS ; CRYSTAL-STRUCTURE ; EFFICIENT EPOXIDATION ; PROPYLENE-OXIDE ; IN-SITU ; OXIDATION ; POLYOXOMETALATE ; COMPLEXES ; ALCOHOLS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000349315200061 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6087]  |
| 专题 | 青岛生物能源与过程研究所_多相催化转化团队 |
| 作者单位 | 1.Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Peoples R China 2.Tech Univ Munich, Catalysis Res Ctr, Mol Catalysis Chair Inorgan Chem, D-85747 Garching, Germany 3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Ming-Dong,Liu, Mei-Ju,Huang, Liang-Liang,et al. Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts[J]. GREEN CHEMISTRY,2015,17(2):1186-1193. |
| APA | Zhou, Ming-Dong.,Liu, Mei-Ju.,Huang, Liang-Liang.,Zhang, Jian.,Wang, Jing-Yun.,...&Zang, Shu-Liang.(2015).Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts.GREEN CHEMISTRY,17(2),1186-1193. |
| MLA | Zhou, Ming-Dong,et al."Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts".GREEN CHEMISTRY 17.2(2015):1186-1193. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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