Single-ion dominantly conducting polyborates towards high performance electrolytes in lithium batteries
文献类型：期刊论文
| 作者 | Qin, Bingsheng1,2; Liu, Zhihong2; Zheng, Jie2; Hu, Pu2; Ding, Guoliang2 ; Zhang, Chuanjian2; Zhao, Jianghui2; Kong, Desheng1; Cui, Guanglei2
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| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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| 出版日期 | 2015 |
| 卷号 | 3期号:15页码:7773-7779 |
| 英文摘要 | A couple of thermally stable polyborate salts, polymeric lithium pentaerythrite borate (PLPB) and polymeric lithium di(trimethylolpropane) borate (PLDB), for applications in lithium ion batteries were synthesized via a facile one-step reaction in aqueous solution. Both the lithium polyborate salts exhibited a high thermal decomposition temperature at about 240 degrees C. Besides, their corresponding single-ion dominantly conducting gel polymer electrolytes of ethylene carbonate (EC) and dimethyl carbonate (DMC) (1 : 1, v/v) swollen PLPB@PVDF-HFP (poly(vinylidenefluoride-co-hexafluoropropene)) and PLDB@PVDF-HFP exhibited favorable ionic conductivity over a wide temperature range, superior electrochemical stability, high lithium ion transference number and Al passivating ability. The Li/LiFePO4 batteries using these single-ion dominantly conducting electrolytes exhibited stable charge-discharge behavior and excellent cycling performance both at room temperature and at elevated temperatures. These superior performances could make this class of gel polymer electrolytes very promising candidates for lithium batteries especially at elevated temperatures. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Materials Science |
| 关键词[WOS] | GEL POLYMER ELECTROLYTE ; LIPF6-BASED ELECTROLYTES ; TRANSFERENCE NUMBERS ; NONAQUEOUS SOLUTIONS ; THERMAL-STABILITY ; LIBOB EC/DEC ; SALT ; LIPF6 ; DECOMPOSITION ; COMPOSITE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000352441100014 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6424]  |
| 专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
| 作者单位 | 1.Qufu Normal Univ, Sch Chem & Chem Engn, Shandong Prov Key Lab Life Organ Anal, Qufu 273165, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Key Lab Solar Energy & Energy Storage, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, Bingsheng,Liu, Zhihong,Zheng, Jie,et al. Single-ion dominantly conducting polyborates towards high performance electrolytes in lithium batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015,3(15):7773-7779. |
| APA | Qin, Bingsheng.,Liu, Zhihong.,Zheng, Jie.,Hu, Pu.,Ding, Guoliang.,...&Cui, Guanglei.(2015).Single-ion dominantly conducting polyborates towards high performance electrolytes in lithium batteries.JOURNAL OF MATERIALS CHEMISTRY A,3(15),7773-7779. |
| MLA | Qin, Bingsheng,et al."Single-ion dominantly conducting polyborates towards high performance electrolytes in lithium batteries".JOURNAL OF MATERIALS CHEMISTRY A 3.15(2015):7773-7779. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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