Pd(OAc)2@SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyaura cross-coupling reaction in aqueous media
文献类型：期刊论文
| 作者 | Rostamnia, Sadegh1; Xin, Hongchuan2 |
| 刊名 | APPLIED ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2013-06-01 |
| 卷号 | 27期号:6页码:348-352 |
| 关键词 | Suzuki-Miyaura cross-coupling heterogeneous catalyst mesoporous nanoreactor Pd@SBA-15 PrEn transition metal complex |
| 英文摘要 | A series of ordered mesoporous organic-inorganic hybrid material was designed by using the amine-functionalized SBA-15 (PdX2@SBA-15/NY, Y=1, 2) as solid support for palladium complexes. Among them, the Pd(OAc)2/ethylenediamine complex encapsulated into SBA-15 (Pd(OAc)2@SBA-15/PrEn or Pd(OAc)2@SBA-15/PrNHEtNH2) exhibits higher activity and selectivity toward Suzuki cross-coupling reaction under aerobic conditions and water solvent mixture. The SBA-15/PrEn supported palladium pre-catalyst could be separated easily from reaction products and used repetitively several times, showing its superiority over homogeneous catalysts for industrial and chemical applications. Copyright (c) 2013 John Wiley & Sons, Ltd. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CARBAPALLADACYCLE COMPLEX ; HETEROGENEOUS CATALYST ; PALLADIUM CATALYST ; MESOPOROUS SILICA ; HECK REACTION ; WATER ; EFFICIENT ; GREEN ; NANOPARTICLES ; DERIVATIVES |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000319516500006 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/5995]  |
| 专题 | 青岛生物能源与过程研究所_科技发展部 |
| 作者单位 | 1.Univ Maragheh, Dept Chem, ONG, Fac Sci, Maragheh, Iran 2.Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Rostamnia, Sadegh,Xin, Hongchuan. Pd(OAc)2@SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyaura cross-coupling reaction in aqueous media[J]. APPLIED ORGANOMETALLIC CHEMISTRY,2013,27(6):348-352. |
| APA | Rostamnia, Sadegh,&Xin, Hongchuan.(2013).Pd(OAc)2@SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyaura cross-coupling reaction in aqueous media.APPLIED ORGANOMETALLIC CHEMISTRY,27(6),348-352. |
| MLA | Rostamnia, Sadegh,et al."Pd(OAc)2@SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyaura cross-coupling reaction in aqueous media".APPLIED ORGANOMETALLIC CHEMISTRY 27.6(2013):348-352. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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