Aqueous-phase hydrogenation of biomass-derived itaconic acid to methyl-gamma-butyrolactone over Pd/C catalysts: Effect of pretreatments of active carbon
文献类型:期刊论文
作者 | Li, Sha1,2; Wang, Xicheng2![]() ![]() ![]() |
刊名 | CATALYSIS COMMUNICATIONS
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出版日期 | 2015-02-10 |
卷号 | 61页码:92-96 |
关键词 | Biomass Itaconic acid Methyl-gamma-butyrolactone Hydrogenation Pd/C |
英文摘要 | The effect of active carbon pretreatment on the catalytic performance of Pd/C catalysts in the hydrogenation of itaconic acid was studied. The catalysts were prepared by deposition-precipitation and characterized by XRD, BET, NH3-TPD, TEM and FT-IR. Due to the modification of the surface functional groups, surface structure and surface acidities of active carbon via pretreatment, the Pd/C catalysts showed varied catalytic performances. High dispersion and uniform particles were conducive to the excellent activity of Pd/C catalyst with support copretreated with HNO3 and NaClO, which exhibited 89.5% selectivity towards methyl-gamma-butyrolactone at 180 degrees C, 4 MPa H-2 for 20 h. (C) 2014 Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical |
研究领域[WOS] | Chemistry |
关键词[WOS] | SUCCINIC ACID ; PLATFORM CHEMICALS ; LEVULINIC ACID ; VALEROLACTONE ; CONVERSION ; 1,4-BUTANEDIOL ; NANOPARTICLES ; ELECTRODES ; BIO |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000348884700020 |
公开日期 | 2015-12-24 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/6103] ![]() |
专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
作者单位 | 1.Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Sha,Wang, Xicheng,Liu, Xiaoran,et al. Aqueous-phase hydrogenation of biomass-derived itaconic acid to methyl-gamma-butyrolactone over Pd/C catalysts: Effect of pretreatments of active carbon[J]. CATALYSIS COMMUNICATIONS,2015,61:92-96. |
APA | Li, Sha,Wang, Xicheng,Liu, Xiaoran,Xu, Guoqiang,Han, Sheng,&Mu, Xindong.(2015).Aqueous-phase hydrogenation of biomass-derived itaconic acid to methyl-gamma-butyrolactone over Pd/C catalysts: Effect of pretreatments of active carbon.CATALYSIS COMMUNICATIONS,61,92-96. |
MLA | Li, Sha,et al."Aqueous-phase hydrogenation of biomass-derived itaconic acid to methyl-gamma-butyrolactone over Pd/C catalysts: Effect of pretreatments of active carbon".CATALYSIS COMMUNICATIONS 61(2015):92-96. |
入库方式: OAI收割
来源:青岛生物能源与过程研究所
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