中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Photo-catalytic properties of doped or substituted polyaniline-coated Fe3O4 nanoparticles

文献类型:期刊论文

作者Zhang, Fan1,2; Song, Weijie2; Zhao, Zongshan3; Cheng, Yang4
刊名JOURNAL OF NANOPARTICLE RESEARCH
出版日期2014-10-01
卷号16期号:10
关键词Magnetic nanoparticles Core/shell Photo-catalytic activity Dopant Substituent
英文摘要In this work, doped and substituted polyaniline (PANI)-coated Fe3O4 nanoparticles were synthesized. The diameter of Fe3O4 core was similar to 430 nm, and the thickness of PANI shell was similar to 20 nm. Their photo-catalytic properties for methyl orange were investigated under natural light illumination. The photo-catalytic activity sequence of three doped PANI/Fe3O4 nanoparticles is as follows: iodine doping > without doping > graphite powder doping This should be due to the difference of structure, conductivity, and band gap resulting from the dopants. The photo-catalytic activity of five substituted PANI/Fe3O4 nanoparticles followed the order of poly(1,2-diaminobenzene) > poly(o-toluidine) > poly(1,3-diaminobenzene) > PANI > polydiphenylamine. The effects of steric hindrance, activated ability, and conjugation of the substituents on the photo-catalytic properties were discussed. The ESR results suggested that O-2 and H2O2 dissolved in the solutions were important factors on the photo-degradation, and the center dot OH generated via h(+)-mediated pathwaywas the key oxidizing substance.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]PHOTOCATALYTIC DEGRADATION ; CONJUGATED POLYMERS ; GRAFT-POLYMERIZATION ; METAL IONS ; COMPOSITE ; EFFICIENT ; REMOVAL ; WATER ; TIO2 ; MICROSPHERES
收录类别SCI
语种英语
WOS记录号WOS:000348051000001
公开日期2015-12-24
源URL[http://ir.qibebt.ac.cn/handle/337004/6145]  
专题青岛生物能源与过程研究所_绿色化学催化团队
作者单位1.Nanjing Agr Univ, Coll Sci, Nanjing 210095, Jiangsu, Peoples R China
2.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China
4.Wuhan Univ Sci & Technol, Coll Chem Engn & Technol, Wuhan 430083, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Fan,Song, Weijie,Zhao, Zongshan,et al. Photo-catalytic properties of doped or substituted polyaniline-coated Fe3O4 nanoparticles[J]. JOURNAL OF NANOPARTICLE RESEARCH,2014,16(10).
APA Zhang, Fan,Song, Weijie,Zhao, Zongshan,&Cheng, Yang.(2014).Photo-catalytic properties of doped or substituted polyaniline-coated Fe3O4 nanoparticles.JOURNAL OF NANOPARTICLE RESEARCH,16(10).
MLA Zhang, Fan,et al."Photo-catalytic properties of doped or substituted polyaniline-coated Fe3O4 nanoparticles".JOURNAL OF NANOPARTICLE RESEARCH 16.10(2014).

入库方式: OAI收割

来源:青岛生物能源与过程研究所

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