One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni-Co-Al Mixed Oxide Catalysts Under Mild Conditions
文献类型：期刊论文
| 作者 | Yao, Shengxi1; Wang, Xicheng1; Jiang, Yijun1; Wu, Feng1; Chen, Xinguo1; Mu, Xindong1,2
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| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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| 出版日期 | 2014-02-01 |
| 卷号 | 2期号:2页码:173-180 |
| 关键词 | 5-Hydroxymethylfurfural 1 Mixed metal oxide catalyst NiO CoO Furan derivatives 2 6-Hexanetriol |
| 英文摘要 | The conversion of biomass-derived 5-hydroxymethylfurfural (HMF) was examined over Ni Co Al mixed oxide catalysts derived from corresponding hydrotalcite-like compounds (HTlcs). 1,2,6-Hexanetriol (1,2,6-HT) was obtained in 64.5% yield under mild reaction conditions. The catalysts were characterized by X-ray. powder diffraction (XRD), CO2 temperature-programthed desorption (CO2 TPD), N2 physical adsorption, and H2 temperatureprogrammed reduction (H2 TPR), and the reaction product distribution was correlated with the catalyst composition and reaction conditions. The reaction pathway was proposed based on the results. In all cases, the conversion of HMF proceeds according to a pathway that begins with the aldehyde group being hydrogenated to form 2,5-dihydroxymethylfuran (2,5-DHF). This product then undergoes a ring-opening reaction to form 1,2,6-HT. A synergetic effect between Ni and Co was observed, which significantly promoted catalytic activity and selectivity. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Multidisciplinary ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | CYCLIC ETHERS ; HYDROGENOLYSIS ; HYDROTALCITE ; MECHANISM ; ALCOHOL ; NOX ; CU |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000330812400009 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6319]  |
| 专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Qingdao Engn Res Ctr Biomass Green Chem Convers, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Shengxi,Wang, Xicheng,Jiang, Yijun,et al. One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni-Co-Al Mixed Oxide Catalysts Under Mild Conditions[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2014,2(2):173-180. |
| APA | Yao, Shengxi,Wang, Xicheng,Jiang, Yijun,Wu, Feng,Chen, Xinguo,&Mu, Xindong.(2014).One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni-Co-Al Mixed Oxide Catalysts Under Mild Conditions.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2(2),173-180. |
| MLA | Yao, Shengxi,et al."One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni-Co-Al Mixed Oxide Catalysts Under Mild Conditions".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 2.2(2014):173-180. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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