Direct alpha-Alkylation of Ketones with Alcohols in Water
文献类型：期刊论文
| 作者 | Xu, Guoqiang1 ; Li, Qiong1,2; Feng, Jiange2; Liu, Qiang1; Zhang, Zuojun1; Wang, Xicheng1; Zhang, Xiaoyun2; Mu, Xindong1
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| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2014 |
| 卷号 | 7期号:1页码:105-109 |
| 关键词 | alcohols alkylations aqueous-phase reforming heterogeneous catalysis ketones |
| 英文摘要 | The direct alpha-alkylation of ketones with alcohols has emerged as a new green protocol to construct C-C bonds with H2O as the sole byproduct. In this work, a very simple and convenient Pd/C catalytic system for the direct alpha-alkylation of ketones with primary alcohols in pure water is developed. Based on this catalytic system, aqueous mixtures of dilute acetone, 1-butanol, and ethanol (mimicking ABE fermentation products) can be directly transformed into C-5-C-11 or longer-chain ketones and alcohols, which are precursors to fuels. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CATALYZED ALKYLATION ; TRANSFORMATIONS ; SOLVENT ; FUELS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000336802400012 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6327]  |
| 专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.China Univ Petr, Coll Sci, Qingdao 266555, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Guoqiang,Li, Qiong,Feng, Jiange,et al. Direct alpha-Alkylation of Ketones with Alcohols in Water[J]. CHEMSUSCHEM,2014,7(1):105-109. |
| APA | Xu, Guoqiang.,Li, Qiong.,Feng, Jiange.,Liu, Qiang.,Zhang, Zuojun.,...&Mu, Xindong.(2014).Direct alpha-Alkylation of Ketones with Alcohols in Water.CHEMSUSCHEM,7(1),105-109. |
| MLA | Xu, Guoqiang,et al."Direct alpha-Alkylation of Ketones with Alcohols in Water".CHEMSUSCHEM 7.1(2014):105-109. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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