Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer
文献类型:期刊论文
作者 | Peng, Gongming; Wang, Xicheng; Chen, Xiufang; Jiang, Yijun; Mu, Xindong![]() |
刊名 | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
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出版日期 | 2014-09-25 |
卷号 | 20期号:5页码:2641-2645 |
关键词 | Zirconia-supported niobia 1,2-Propanediol Hydrogen transfer |
英文摘要 | Vapor-phase catalytic dehydration of 1,2-propanediol was investigated over Zirconia-supported niobia catalysts. The catalysts exhibit selectivity favoring propanol (approximately 39%) at 85.0% 1,2-propanediol conversion at 290 degrees C under 1 atm N-2. The ZrNbO catalysts were analyzed by various techniques; the results indicated that the active sites were weak Bronsted acid sites. A dehydration and hydrogen transfer mechanism was also proposed. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Multidisciplinary ; Engineering, Chemical |
研究领域[WOS] | Chemistry ; Engineering |
关键词[WOS] | GLYCEROL HYDROGENOLYSIS ; SELECTIVE OXIDATION ; BASE ; DIHYDROXYACETONE ; BIOPROPANOLS ; ACROLEIN ; ACIDITY ; REOX |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000339692100004 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/6362] ![]() |
专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
作者单位 | Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Peng, Gongming,Wang, Xicheng,Chen, Xiufang,et al. Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,2014,20(5):2641-2645. |
APA | Peng, Gongming,Wang, Xicheng,Chen, Xiufang,Jiang, Yijun,&Mu, Xindong.(2014).Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer.JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,20(5),2641-2645. |
MLA | Peng, Gongming,et al."Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer".JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 20.5(2014):2641-2645. |
入库方式: OAI收割
来源:青岛生物能源与过程研究所
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