中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer

文献类型:期刊论文

作者Peng, Gongming; Wang, Xicheng; Chen, Xiufang; Jiang, Yijun; Mu, Xindong
刊名JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
出版日期2014-09-25
卷号20期号:5页码:2641-2645
关键词Zirconia-supported niobia 1,2-Propanediol Hydrogen transfer
英文摘要

Vapor-phase catalytic dehydration of 1,2-propanediol was investigated over Zirconia-supported niobia catalysts. The catalysts exhibit selectivity favoring propanol (approximately 39%) at 85.0% 1,2-propanediol conversion at 290 degrees C under 1 atm N-2. The ZrNbO catalysts were analyzed by various techniques; the results indicated that the active sites were weak Bronsted acid sites. A dehydration and hydrogen transfer mechanism was also proposed. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Multidisciplinary ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]GLYCEROL HYDROGENOLYSIS ; SELECTIVE OXIDATION ; BASE ; DIHYDROXYACETONE ; BIOPROPANOLS ; ACROLEIN ; ACIDITY ; REOX
收录类别SCI
语种英语
WOS记录号WOS:000339692100004
源URL[http://ir.qibebt.ac.cn/handle/337004/6362]  
专题青岛生物能源与过程研究所_绿色化学催化团队
作者单位Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China
推荐引用方式
GB/T 7714
Peng, Gongming,Wang, Xicheng,Chen, Xiufang,et al. Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,2014,20(5):2641-2645.
APA Peng, Gongming,Wang, Xicheng,Chen, Xiufang,Jiang, Yijun,&Mu, Xindong.(2014).Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer.JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,20(5),2641-2645.
MLA Peng, Gongming,et al."Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer".JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 20.5(2014):2641-2645.

入库方式: OAI收割

来源:青岛生物能源与过程研究所

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