Polydimethylsiloxane: A General Matrix for High-Performance Chromatographic NMR Spectroscopy
文献类型：期刊论文
| 作者 | Huang, Shaohua1 ; Gao, Jun1; Wu, Rui2; Li, Shengying1; Bai, Zhengwu2
|
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2014-10-20 |
| 卷号 | 53期号:43页码:11592-11595 |
| 关键词 | analytical methods matrices mixture analysis NMR spectroscopy poly(dimethylsiloxane) |
| 英文摘要 | The detection and structural characterization of the components of a mixture is a challenging task. Therefore, the development of a facile and general method that enables both the separation and the structural characterization of the components is desired. Diffusion-ordered NMR spectroscopy (DOSY) with the aid of a matrix is a promising tool for this purpose. However, because the currently existing matrices only separate limited components, the application of the DOSY technique is restricted. Herein we introduce a new versatile matrix, poly(dimethylsiloxane), which can fully separate many mixtures of different structural types by liquid-state NMR spectroscopy. With poly(dimethylsiloxane), liquid-state chromatographic NMR spectroscopy could become a general approach for the structural elucidation of mixtures of compounds. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | DIFFUSION-ORDERED SPECTROSCOPY ; CROSS-COUPLING REACTIONS ; STATIONARY PHASES ; SMALL MOLECULES ; RESOLUTION ; MIXTURES ; MICELLES ; POLYVINYLPYRROLIDONE ; CHEMISTRY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000343870400035 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6229]  |
| 专题 | 青岛生物能源与过程研究所_酶工程团队 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430073, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Shaohua,Gao, Jun,Wu, Rui,et al. Polydimethylsiloxane: A General Matrix for High-Performance Chromatographic NMR Spectroscopy[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(43):11592-11595. |
| APA | Huang, Shaohua,Gao, Jun,Wu, Rui,Li, Shengying,&Bai, Zhengwu.(2014).Polydimethylsiloxane: A General Matrix for High-Performance Chromatographic NMR Spectroscopy.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(43),11592-11595. |
| MLA | Huang, Shaohua,et al."Polydimethylsiloxane: A General Matrix for High-Performance Chromatographic NMR Spectroscopy".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.43(2014):11592-11595. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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