Lactic acid production from glucose over polymer catalysts in aqueous alkaline solution under mild conditions
文献类型：期刊论文
| 作者 | Wang, Xincheng1; Song, Yanlei1; Huang, Chongpin1; Liang, Fengbing2; Chen, Biaohua1 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2014-09-01 |
| 卷号 | 16期号:9页码:4234-4240 |
| 英文摘要 | Methods for the transformation of carbohydrates into tactic acid (LA), which is a versatile platform chemical, have been widely investigated. These methods typically employ harsh reaction conditions, especially when water is used as a solvent. In the present study, a one-pot route that uses polymerizates of imidazole and epichlorohydrin ([IMEP]Cl) as catalysts to convert glucose to LA in water was described. The highest LA yield of 63% (mol%) was achieved with 99% glucose conversion at 100 degrees C in 50 mM NaOH solution. Compared to previous reports, the process has lower reaction temperatures and lower concentration of alkaline. A possible reaction mechanism was proposed that the coordination between the weak Lewis acid centers of the polymer with the electronegative oxygens on the intermediates efficiently facilitated the rate determining step during the reaction. This route allows for facile catalyst recovery and recycling white providing a new strategy for carbohydrate conversion. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | HYDROTHERMAL CONVERSION ; CARBOHYDRATE BIOMASS ; CHEMICAL-PROCESS ; IONIC LIQUIDS ; WATER ; SALTS ; SUGARS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000341282200025 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6727]  |
| 专题 | 青岛生物能源与过程研究所_酶工程团队 |
| 作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xincheng,Song, Yanlei,Huang, Chongpin,et al. Lactic acid production from glucose over polymer catalysts in aqueous alkaline solution under mild conditions[J]. GREEN CHEMISTRY,2014,16(9):4234-4240. |
| APA | Wang, Xincheng,Song, Yanlei,Huang, Chongpin,Liang, Fengbing,&Chen, Biaohua.(2014).Lactic acid production from glucose over polymer catalysts in aqueous alkaline solution under mild conditions.GREEN CHEMISTRY,16(9),4234-4240. |
| MLA | Wang, Xincheng,et al."Lactic acid production from glucose over polymer catalysts in aqueous alkaline solution under mild conditions".GREEN CHEMISTRY 16.9(2014):4234-4240. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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