Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties
文献类型：期刊论文
| 作者 | Xu, Jiakun1,2; Sun, Xiaochun3; Yan, Xingchen2,4; Wang, Shuaiyu1; Sun, Mi1 |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2013-11-01 |
| 卷号 | 37页码:49-53 |
| 关键词 | 3 Hydrothermal synthesis Crystal structure Coordination polymer Luminescence 5-Bis(benzoimidazo-1-ly)pyridine |
| 英文摘要 | Two new metal coordination polymers [Cd-2(ba)(4)(L)(2)](n) (1) and [Zn(tda)(L)](n) (2) [Hba = benzoic acid, H(2)tda = 2,5-thiophenedicarboxylic acid and L = 3,5-bis(benzoimidazo-1-ly)pyridine] have been successfully synthesized and structurally characterized by IR, elemental analysis. X-ray powder diffraction and X-ray single-crystal diffraction. For complex 1, two Cd(II) ions and four ba ligands form the dimetal clusters, which are further connected through the L ligands to give rise to a uninodal 3-connected hcb Shubnikov hexagonal plane net with the 6(3) topology. Complex 2 features the 3-connected topological net with 8(2) . 10 topology (so-called "tongue-and groove" structure). The Zn(II) node together with the four surrounding coordinated ligands form a typical T-shaped molecular bilayer motif, which is rarely reported previously. Their X-ray powder diffraction pattems were then carried out to confirm the validity of the crystal structures. In addition, the luminescent properties of 1 and 2 are investigated in the solid state at room temperature, and the thermogravimetric analyses were carried out to study the thermal stability of the two complexes. (C) 2013 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | METAL-ORGANIC FRAMEWORKS ; MAGNETIC-PROPERTIES ; POLYMERS ; LIGAND ; TOPOLOGIES ; DIVERSITY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000328180900012 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6045]  |
| 专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
| 作者单位 | 1.Chinese Acad Fishery Sci, Yellow Sea Fisheries Res Inst, Minist Agr, Key Lab Sustainable Dev Marine Fisheries, Qingdao 266071, Peoples R China 2.Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Peoples R China 3.Natl Oceanog Ctr, Qingdao 266071, Peoples R China 4.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Jiakun,Sun, Xiaochun,Yan, Xingchen,et al. Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2013,37:49-53. |
| APA | Xu, Jiakun,Sun, Xiaochun,Yan, Xingchen,Wang, Shuaiyu,&Sun, Mi.(2013).Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties.INORGANIC CHEMISTRY COMMUNICATIONS,37,49-53. |
| MLA | Xu, Jiakun,et al."Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties".INORGANIC CHEMISTRY COMMUNICATIONS 37(2013):49-53. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。