Polythiophene with oligopeptide side chain: preparation and nano- structure
文献类型：期刊论文
| 作者 | Wang, Xiao1 ; Gong, Ruiying1; Song, Yubao2; Li, Ming2; Mu, Youbing1; Guo, Zongxia1; Wan, Xiaobo1; Jiang, Wei3
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| 刊名 | SUPRAMOLECULAR CHEMISTRY
 |
| 出版日期 | 2013-12-01 |
| 卷号 | 25期号:12页码:842-847 |
| 关键词 | self-assembly oligopeptide polythiophene nanorod |
| 英文摘要 | This manuscript describes the first example of nanorods formation of an oligopeptide-modified polythiophene (PTh). The oligopeptide-modified monomer was carefully engineered in such a way to keep both high solubility and the ability for self-assembly. A terthiophene with a clickable side chain on the middle thiophene ring and two octyl side chains on the terminal thiophene rings was synthesised to guarantee the solubility; a tetrapeptide (N-3-GVGV-OMe) was chosen to provide self-assembly capability. The monomer obtained by click chemistry showed both high solubility and the ability to form organogels. The monomer was easily polymerised either in solution state or in organogel state to give the corresponding PTh with oligopeptide side chain. The size of the nanorods could be controlled by adjusting the reaction conditions. The formation of the nano-structure was attributed to the H-bonding between oligopeptide side chain and its interaction with Fe (II) ion. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CONDUCTING POLYMER ; BLOCK-COPOLYMERS ; CHEMICAL SENSORS ; AQUEOUS-SOLUTION ; NANOSTRUCTURES ; NANOCOMPOSITE ; NANOSPINDLES ; THIOPHENE) ; NANOWIRES ; PEPTIDES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000333569300009 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/5979]  |
| 专题 | 青岛生物能源与过程研究所_生物基及仿生高分子材料团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat CAS, Qingdao 266101, Shandong, Peoples R China 2.Qingdao Univ Sci & Technol, Dept Chem, Qingdao 26604, Shandong, Peoples R China 3.Nanjing Univ, Natl Engn Res Ctr Organ Pollut Control & Resource, State Key Lab Pollut & Resource Reuse, Sch Environm, Nanjing 210023, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xiao,Gong, Ruiying,Song, Yubao,et al. Polythiophene with oligopeptide side chain: preparation and nano- structure[J]. SUPRAMOLECULAR CHEMISTRY,2013,25(12):842-847. |
| APA | Wang, Xiao.,Gong, Ruiying.,Song, Yubao.,Li, Ming.,Mu, Youbing.,...&Jiang, Wei.(2013).Polythiophene with oligopeptide side chain: preparation and nano- structure.SUPRAMOLECULAR CHEMISTRY,25(12),842-847. |
| MLA | Wang, Xiao,et al."Polythiophene with oligopeptide side chain: preparation and nano- structure".SUPRAMOLECULAR CHEMISTRY 25.12(2013):842-847. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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