Surface-Induced Diastereomeric Complex Formation of a Nucleoside at the Liquid/Solid Interface: Stereoselective Recognition and Preferential Adsorption
文献类型：期刊论文
| 作者 | Guo, Zongxia1,4 ; De Cat, Inge1; Van Averbeke, Bernard3; Ghijsens, Elke1; Lin, Jianbin2; Xu, Hong1; Wang, Guojie1; Hoeben, Freek J. M.2; Tomovic, Zeljko2; Lazzaroni, Roberto3
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| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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| 出版日期 | 2013-07-03 |
| 卷号 | 135期号:26页码:9811-9819 |
| 英文摘要 | With the aim of achieving surface-mediated enantioselective adsorption, the self-assembly of chiral oligo(p-phenylenevinylene) (OPV3T) with nucleosides is investigated at the liquid/solid interface by means of scanning tunneling microscopy and molecular modeling. OPV3T enantiomers form mirror related hexameric rosette patterns. The DNA nucleoside, thymidine, does not self-assemble into stable adlayers but coadsorbs with OPV3T on the surface, leading to a pattern transformation of OPV3T from rosettes to dimers, and a change in chiral expression as well Diastereoselective recognition between OPV3T and thymidine enantiomers can be used to resolve thymidine enantiomers at an achiral surface with an OPV3T enantiomer as the resolving agent. The impact of molar ratio and concentration on the self-assembly and chiral resolution is systematically investigated Because there is no interaction between OPV3T and thymidine in solution, the liquid/solid interface acts as the platform for the chiral resolution of thymidine enantiomers. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | SCANNING-TUNNELING-MICROSCOPY ; SPONTANEOUS RESOLUTION ; 2-DIMENSIONAL CRYSTALS ; STEREOGENIC CENTERS ; CHIRAL SEPARATION ; ORGANIC-MOLECULES ; ASSEMBLIES ; ACID ; MONOLAYERS ; HOMOCHIRALITY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000321541800043 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6003]  |
| 专题 | 青岛生物能源与过程研究所_生物基及仿生高分子材料团队 |
| 作者单位 | 1.Katholieke Univ Leuven, Dept Chem, Div Mol Imaging & Photon, B-3001 Louvain, Belgium 2.Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands 3.Univ Mons UMONS, Serv Chim Mat Nouveaux, B-7000 Mons, Belgium 4.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Zongxia,De Cat, Inge,Van Averbeke, Bernard,et al. Surface-Induced Diastereomeric Complex Formation of a Nucleoside at the Liquid/Solid Interface: Stereoselective Recognition and Preferential Adsorption[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2013,135(26):9811-9819. |
| APA | Guo, Zongxia.,De Cat, Inge.,Van Averbeke, Bernard.,Ghijsens, Elke.,Lin, Jianbin.,...&De Feyter, Steven.(2013).Surface-Induced Diastereomeric Complex Formation of a Nucleoside at the Liquid/Solid Interface: Stereoselective Recognition and Preferential Adsorption.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,135(26),9811-9819. |
| MLA | Guo, Zongxia,et al."Surface-Induced Diastereomeric Complex Formation of a Nucleoside at the Liquid/Solid Interface: Stereoselective Recognition and Preferential Adsorption".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 135.26(2013):9811-9819. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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