中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of superporous hydrogels by a postpolymerization foaming protocol and their water absorbent behavior

文献类型:期刊论文

作者Gong, Ruiying; Kang, Ning; Mu, Youbing; Li, Jianzhong; Wan, Xiaobo
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2012-08-15
卷号125期号:4页码:3100-3106
关键词superporous hydrogels prefoaming process swelling absorbent capacity
英文摘要

The rate of swelling is one of the most important parameters of hydrogel polymeric networks; therefore, the objective of this study was to develop a new method to synthesize superporous poly(acrylic acid-co-acrylamide) hydrogels to improve swelling rate. The hydrogel was prepared in the presence of a foaming agent (comprising azodicarbonamide and zinc oxide), using 2,2'-Azobis[2-(2-imidazolin-2-yl)propane] dihydrochloride as the initiator. The N2 released during the polymerization led to the formation of a slightly foamed gel; we refer to the process as a prefoaming process. The obtained gel underwent a further foaming process to form a superporous hydrogel. Unlike in existing methods, the consistent time control of the foaming agent addition and the onset of gelling were not necessary in this simplified gel preparation procedure. The water absorbent behavior of the superporous hydrogels suggested that the polymers obtained from the prefoaming process reached the swelling equilibrium more rapidly than those with little prefoaming, and their absorbent capacity was greater. Scanning electron microscope images show that interconnected pores inside these superporous gels formed capillary channels, which are critical for the fast swelling rate. (C) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Polymer Science
研究领域[WOS]Polymer Science
关键词[WOS]SWELLING BEHAVIOR ; SUPERABSORBENT HYDROGELS ; MACROPOROUS HYDROGELS ; POLYMERIZATION ; ACRYLATE)
收录类别SCI
语种英语
WOS记录号WOS:000303596200074
源URL[http://ir.qibebt.ac.cn/handle/337004/6067]  
专题青岛生物能源与过程研究所_生物基及仿生高分子材料团队
作者单位Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式
GB/T 7714
Gong, Ruiying,Kang, Ning,Mu, Youbing,et al. Synthesis of superporous hydrogels by a postpolymerization foaming protocol and their water absorbent behavior[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2012,125(4):3100-3106.
APA Gong, Ruiying,Kang, Ning,Mu, Youbing,Li, Jianzhong,&Wan, Xiaobo.(2012).Synthesis of superporous hydrogels by a postpolymerization foaming protocol and their water absorbent behavior.JOURNAL OF APPLIED POLYMER SCIENCE,125(4),3100-3106.
MLA Gong, Ruiying,et al."Synthesis of superporous hydrogels by a postpolymerization foaming protocol and their water absorbent behavior".JOURNAL OF APPLIED POLYMER SCIENCE 125.4(2012):3100-3106.

入库方式: OAI收割

来源:青岛生物能源与过程研究所

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