中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties

文献类型:期刊论文

作者Jiang, Fei1,2; Wang, Jun1; Li, Jianzhong1; Wang, Ning1; Bao, Xichang1; Wang, Ting1; Yang, Ying1; Lan, Zhenggang1; Yang, Renqiang1
刊名EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
出版日期2013
期号3页码:375-380
关键词Self-assembly Nanostructures Cage compounds Electrochemistry Palladium N ligands
英文摘要Functional nanosized cage complexes with an octahedral framework have been synthesized by the facile self-assembly reactions of six 90 PdII-containing compounds {[Pd(dppf)(OTf)(2)] or [Pd(PPh3)(OTf)(2)], dppf = 1,1'-bis(diphenylphosphanyl) ferrocene, OTf = trifluoromethylsulfonate} and four 120 degrees functional tritopic ligands [2,4,6-tri(4-pyridyl)-1,3,5-triazine] in acetone. Diffusion-ordered NMR spectroscopy (DOSY) and AFM images clarify the formation of 3-4 nm nanoparticles. These highly symmetrical cage complexes are discrete, face-directed, functional nanoparticles with symmetrical octahedral structures. The self-assembled functional cage complexes exhibit interesting electrochemical activities, and thus will potentially be useful in the catalysis of redox reactions, the encapsulation of sizeable guest molecules and the control of organic synthetic reactions.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]COORDINATION CAGE ; MOLECULAR ARCHITECTURE ; BIOMIMETIC MATERIALS ; BUILDING-BLOCKS ; METALLODENDRIMERS ; CONSTRUCTION ; CHEMISTRY ; PHOTODIMERIZATION ; INCLUSION ; COPOLYMER
收录类别SCI
语种英语
WOS记录号WOS:000316284700006
公开日期2015-12-24
源URL[http://ir.qibebt.ac.cn/handle/337004/5943]  
专题青岛生物能源与过程研究所_先进有机功能材料团队
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Jiang, Fei,Wang, Jun,Li, Jianzhong,et al. Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013(3):375-380.
APA Jiang, Fei.,Wang, Jun.,Li, Jianzhong.,Wang, Ning.,Bao, Xichang.,...&Yang, Renqiang.(2013).Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(3),375-380.
MLA Jiang, Fei,et al."Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .3(2013):375-380.

入库方式: OAI收割

来源:青岛生物能源与过程研究所

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