Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties
文献类型：期刊论文
| 作者 | Jiang, Fei1,2; Wang, Jun1 ; Li, Jianzhong1; Wang, Ning1; Bao, Xichang1; Wang, Ting1; Yang, Ying1; Lan, Zhenggang1; Yang, Renqiang1
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| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2013 |
| 期号 | 3页码:375-380 |
| 关键词 | Self-assembly Nanostructures Cage compounds Electrochemistry Palladium N ligands |
| 英文摘要 | Functional nanosized cage complexes with an octahedral framework have been synthesized by the facile self-assembly reactions of six 90 PdII-containing compounds {[Pd(dppf)(OTf)(2)] or [Pd(PPh3)(OTf)(2)], dppf = 1,1'-bis(diphenylphosphanyl) ferrocene, OTf = trifluoromethylsulfonate} and four 120 degrees functional tritopic ligands [2,4,6-tri(4-pyridyl)-1,3,5-triazine] in acetone. Diffusion-ordered NMR spectroscopy (DOSY) and AFM images clarify the formation of 3-4 nm nanoparticles. These highly symmetrical cage complexes are discrete, face-directed, functional nanoparticles with symmetrical octahedral structures. The self-assembled functional cage complexes exhibit interesting electrochemical activities, and thus will potentially be useful in the catalysis of redox reactions, the encapsulation of sizeable guest molecules and the control of organic synthetic reactions. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | COORDINATION CAGE ; MOLECULAR ARCHITECTURE ; BIOMIMETIC MATERIALS ; BUILDING-BLOCKS ; METALLODENDRIMERS ; CONSTRUCTION ; CHEMISTRY ; PHOTODIMERIZATION ; INCLUSION ; COPOLYMER |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000316284700006 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/5943]  |
| 专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Fei,Wang, Jun,Li, Jianzhong,et al. Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013(3):375-380. |
| APA | Jiang, Fei.,Wang, Jun.,Li, Jianzhong.,Wang, Ning.,Bao, Xichang.,...&Yang, Renqiang.(2013).Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(3),375-380. |
| MLA | Jiang, Fei,et al."Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .3(2013):375-380. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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