Manipulating backbone structure with various conjugated spacers to enhance photovoltaic performance of D-A-type two-dimensional copolymerse
文献类型：期刊论文
| 作者 | Dang, Dongfeng1; Xiao, Manjun1,3; Zhou, Pei1; Shi, Junwei1; Tao, Qiang1,2; Tan, Hua1; Wang, Yafei1; Bao, Xichang3 ; Liu, Yu1; Wang, Ergang2
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| 刊名 | ORGANIC ELECTRONICS
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| 出版日期 | 2014-11-01 |
| 卷号 | 15期号:11页码:2876-2884 |
| 关键词 | Polymer solar cells Two-dimensional copolymers Conjugated spacers Photovoltaic properties |
| 英文摘要 | A class of low band-gap two-dimensional conjugated polymers of PBDTT-FQ PBDTT-TQ PBDTT-BTQ and PBDTT-TTQ was designed and synthesized, which contains the same di(alkylthiophene)-substituted benzo[1,2-b:4,5-b']dithiophene (BDTT) and 6,7-difluoro-quinoxaline (Q) units, as well as various conjugated spacers of furan, thiophene, bithiophene and thieno[3,2-b]thiophene in the main chain. Significant effect of the varied spacers between the BDTT and Q units on the thermal, optical, electrochemical and photovoltaic properties was investigated and observed for these two-dimensional copolymers in the polymer solar cells. The maximum power conversion efficiency of 5.9% with a short circuit current of 13.7 mA/cm(2) and a fill factor of 0.56 was obtained for the PBDTT-TQ with thiophene spacer in the bulk hetero-junction PSCs using [6,6]-phenyl-C-71-butyric acid methyl ester as acceptor. (C) 2014 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| 类目[WOS] | Materials Science, Multidisciplinary ; Physics, Applied |
| 研究领域[WOS] | Materials Science ; Physics |
| 关键词[WOS] | POLYMER SOLAR-CELLS ; OPEN-CIRCUIT VOLTAGE ; BULK-HETEROJUNCTION PHOTOVOLTAICS ; THIOPHENE-QUINOXALINE COPOLYMER ; POWER CONVERSION EFFICIENCY ; ORBITAL ENERGY-LEVELS ; FLUORINATED QUINOXALINE ; ORGANIC PHOTOVOLTAICS ; RATIONAL DESIGN ; BENZOTHIADIAZOLE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000344424500033 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6192]  |
| 专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
| 作者单位 | 1.Xiangtan Univ, Minist Educ, Dept Chem, Key Lab Environm Friendly Chem & Applicat, Xiangtan 411105, Peoples R China 2.Chalmers, Dept Chem & Biol Engn Polymer Technol, SE-41296 Gothenburg, Sweden 3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dang, Dongfeng,Xiao, Manjun,Zhou, Pei,et al. Manipulating backbone structure with various conjugated spacers to enhance photovoltaic performance of D-A-type two-dimensional copolymerse[J]. ORGANIC ELECTRONICS,2014,15(11):2876-2884. |
| APA | Dang, Dongfeng.,Xiao, Manjun.,Zhou, Pei.,Shi, Junwei.,Tao, Qiang.,...&Zhu, Weiguo.(2014).Manipulating backbone structure with various conjugated spacers to enhance photovoltaic performance of D-A-type two-dimensional copolymerse.ORGANIC ELECTRONICS,15(11),2876-2884. |
| MLA | Dang, Dongfeng,et al."Manipulating backbone structure with various conjugated spacers to enhance photovoltaic performance of D-A-type two-dimensional copolymerse".ORGANIC ELECTRONICS 15.11(2014):2876-2884. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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