中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Benzothiadiazole - an excellent acceptor for indacenodithiophene based polymer solar cells

文献类型:期刊论文

作者Liu, Deyu1,2; Sun, Liang2; Du, Zhengkun2; Xiao, Manjun2; Gu, Chuantao2; Wang, Ting2; Wen, Shuguang2; Sun, Mingliang1; Yang, Renqiang2
刊名RSC ADVANCES
出版日期2014
卷号4期号:71页码:37934-37940
英文摘要

Two tetradodeoxyphenyl-substituted indacenodithiophene (IDT) based polymers, PIDT3T and PIDTDTBT, were achieved by copolymerizing IDT with terthiophene (3T) or di-2-thienyl-2',1',3'-benzothiadiazole (DTBT). Although these two polymers show significantly different UV-vis absorption spectra and band gaps (2.08 eV and 1.75 eV), the HOMO levels (- 5.35 eV and - 5.30 eV) of these polymers are almost the same. Polymer solar cells (PSCs) based on polymers with the benzothiadiazole (BT) unit show relatively high short-circuit current density (J(sc)) due to the relatively wide and high photo-electronic response and high hole mobility. Thanks to the four long aryl side chains on IDT, the polymer thin film shows an amorphous nature, and the AFM root-mean-square roughness (RMS) value of the polymer/PCBM blend film is only around 0.3 nm which can contribute to the homogenous bulk heterojunction structures without significant phase separation. Finally, decent power conversion efficiency (PCE) of 4.52% is achieved by the benzothiadiazole based polymer and PC71BM composite. By comparison study, we demonstrate why BT is an excellent acceptor unit for indacenodithiophene-based PSCs.

WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]POWER CONVERSION EFFICIENCY ; OPEN-CIRCUIT VOLTAGE ; CONJUGATED POLYMERS ; PHOTOVOLTAIC PROPERTIES ; HIGH-PERFORMANCE ; SEMICONDUCTING POLYMERS ; ORGANIC PHOTOVOLTAICS ; CHARGE-TRANSPORT ; SIDE-CHAINS ; BAND
收录类别SCI
语种英语
WOS记录号WOS:000341454600067
源URL[http://ir.qibebt.ac.cn/handle/337004/6237]  
专题青岛生物能源与过程研究所_先进有机功能材料团队
作者单位1.Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China
2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266100, Peoples R China
推荐引用方式
GB/T 7714
Liu, Deyu,Sun, Liang,Du, Zhengkun,et al. Benzothiadiazole - an excellent acceptor for indacenodithiophene based polymer solar cells[J]. RSC ADVANCES,2014,4(71):37934-37940.
APA Liu, Deyu.,Sun, Liang.,Du, Zhengkun.,Xiao, Manjun.,Gu, Chuantao.,...&Yang, Renqiang.(2014).Benzothiadiazole - an excellent acceptor for indacenodithiophene based polymer solar cells.RSC ADVANCES,4(71),37934-37940.
MLA Liu, Deyu,et al."Benzothiadiazole - an excellent acceptor for indacenodithiophene based polymer solar cells".RSC ADVANCES 4.71(2014):37934-37940.

入库方式: OAI收割

来源:青岛生物能源与过程研究所

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