Benzothiadiazole - an excellent acceptor for indacenodithiophene based polymer solar cells
文献类型:期刊论文
作者 | Liu, Deyu1,2; Sun, Liang2; Du, Zhengkun2; Xiao, Manjun2; Gu, Chuantao2; Wang, Ting2; Wen, Shuguang2; Sun, Mingliang1; Yang, Renqiang2![]() |
刊名 | RSC ADVANCES
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出版日期 | 2014 |
卷号 | 4期号:71页码:37934-37940 |
英文摘要 | Two tetradodeoxyphenyl-substituted indacenodithiophene (IDT) based polymers, PIDT3T and PIDTDTBT, were achieved by copolymerizing IDT with terthiophene (3T) or di-2-thienyl-2',1',3'-benzothiadiazole (DTBT). Although these two polymers show significantly different UV-vis absorption spectra and band gaps (2.08 eV and 1.75 eV), the HOMO levels (- 5.35 eV and - 5.30 eV) of these polymers are almost the same. Polymer solar cells (PSCs) based on polymers with the benzothiadiazole (BT) unit show relatively high short-circuit current density (J(sc)) due to the relatively wide and high photo-electronic response and high hole mobility. Thanks to the four long aryl side chains on IDT, the polymer thin film shows an amorphous nature, and the AFM root-mean-square roughness (RMS) value of the polymer/PCBM blend film is only around 0.3 nm which can contribute to the homogenous bulk heterojunction structures without significant phase separation. Finally, decent power conversion efficiency (PCE) of 4.52% is achieved by the benzothiadiazole based polymer and PC71BM composite. By comparison study, we demonstrate why BT is an excellent acceptor unit for indacenodithiophene-based PSCs. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | POWER CONVERSION EFFICIENCY ; OPEN-CIRCUIT VOLTAGE ; CONJUGATED POLYMERS ; PHOTOVOLTAIC PROPERTIES ; HIGH-PERFORMANCE ; SEMICONDUCTING POLYMERS ; ORGANIC PHOTOVOLTAICS ; CHARGE-TRANSPORT ; SIDE-CHAINS ; BAND |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000341454600067 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/6237] ![]() |
专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
作者单位 | 1.Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266100, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Deyu,Sun, Liang,Du, Zhengkun,et al. Benzothiadiazole - an excellent acceptor for indacenodithiophene based polymer solar cells[J]. RSC ADVANCES,2014,4(71):37934-37940. |
APA | Liu, Deyu.,Sun, Liang.,Du, Zhengkun.,Xiao, Manjun.,Gu, Chuantao.,...&Yang, Renqiang.(2014).Benzothiadiazole - an excellent acceptor for indacenodithiophene based polymer solar cells.RSC ADVANCES,4(71),37934-37940. |
MLA | Liu, Deyu,et al."Benzothiadiazole - an excellent acceptor for indacenodithiophene based polymer solar cells".RSC ADVANCES 4.71(2014):37934-37940. |
入库方式: OAI收割
来源:青岛生物能源与过程研究所
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