Novel wide band-gap polymer utilizing fused hetero-aromatic unit for efficient polymer solar cells and field-effect transistors
文献类型:期刊论文
作者 | Dang, Dongfeng1; Zhou, Pei1; Zhong, Juan1; Fan, Jiang1; Wang, Zongrui3; Wang, Yafei1; Pei, Yong1; Bao, Xichang2![]() ![]() |
刊名 | POLYMER
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出版日期 | 2014-12-15 |
卷号 | 55期号:26页码:6708-6716 |
关键词 | Wide band-gap polymers Polymer solar cells Organic field-effect transistors |
英文摘要 | Novel wide band-gap polymer of PBTFT containing dibenzosexithiophene-alt-bithiophene backbone was designed and synthesized via the Stille cross-coupling reaction. This polymer exhibited good thermal stability, well coplanar backbone and a broad absorption band from 350 nm to 610 nm with a wide optical band-gap of 2.02 eV. The polymer solar cells (PSCs) based on the PBTFT:PC71BM active layer showed the power conversion efficiency of 3.0% with an open circuit voltage of 0.70 V, a short-circuit current of 7.94 mA cm(-2) and a fill factor of 53.98% under the illumination of AM.1.5, 100 mW cm(-2). Holes mobility up to 0.028 cm(2) V-1 s(-1) with an on-off ratio of 1.0 x 10(6) was obtained in the PBTFT-based organic field-effect transistors (OFETs). Our work indicates that the dibenzosexithiophene-alt-bithiophene based copolymer can be efficiently applied in PSCs and OFETs. (C) 2014 Elsevier Ltd. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Polymer Science |
研究领域[WOS] | Polymer Science |
关键词[WOS] | CONJUGATED POLYMERS ; PHOTOVOLTAIC PERFORMANCE ; HIGH-MOBILITY ; SIDE-CHAIN ; SEMICONDUCTING POLYMERS ; RATIONAL DESIGN ; COPOLYMERS ; DIKETOPYRROLOPYRROLE ; DERIVATIVES ; PROGRESS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000346887700009 |
公开日期 | 2015-12-24 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/6292] ![]() |
专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
作者单位 | 1.Xiangtan Univ, Dept Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Dang, Dongfeng,Zhou, Pei,Zhong, Juan,et al. Novel wide band-gap polymer utilizing fused hetero-aromatic unit for efficient polymer solar cells and field-effect transistors[J]. POLYMER,2014,55(26):6708-6716. |
APA | Dang, Dongfeng.,Zhou, Pei.,Zhong, Juan.,Fan, Jiang.,Wang, Zongrui.,...&Zhu, Weiguo.(2014).Novel wide band-gap polymer utilizing fused hetero-aromatic unit for efficient polymer solar cells and field-effect transistors.POLYMER,55(26),6708-6716. |
MLA | Dang, Dongfeng,et al."Novel wide band-gap polymer utilizing fused hetero-aromatic unit for efficient polymer solar cells and field-effect transistors".POLYMER 55.26(2014):6708-6716. |
入库方式: OAI收割
来源:青岛生物能源与过程研究所
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