Electrochemistry and Near-infrared Electrochromism of Electropolymerized Polydithiophenes with beta, beta '-Positions Bridged by Carbonyl or Dicarbonyl Substitute
文献类型：期刊论文
| 作者 | Liu, Wei1; Gu, Chuantao1,2; Wang, Jiuxing1,2; Sun, Mingliang3; Yang, Renqiang1
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| 刊名 | ELECTROCHIMICA ACTA
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| 出版日期 | 2014-10-01 |
| 卷号 | 142页码:108-117 |
| 关键词 | Near-infrared electrochromism Quartz Crystal Microbalance Massogram Cyclopenta[2 Benzo[1 1-b:3 2-b:6 4-b ']dithiophene-4-one 5-b ']dithiophene-4 5-dione |
| 英文摘要 | The beta, beta'-positions carbonyl or dicarbonyl bridged dithiophenes were prepared and electrochemically polymerized into corresponding polymers, polycyclopenta[2,1-b;3,4-b']dithiophen-4-one (PCDK) or polybenzo[1,2-b:6,5-b']dithiophene-4,5-dione (PCD2K), in boron trifluoride diethyl etherate based electrolyte. Potentiostatic and potentiodynamic method's confirmed that the PCDK and PCD2K films can be successfully electrodeposited in high quality with comparable intermolecular spacings at around 3.1 angstrom-3.2 angstrom. The mass changes and ion transport of the two polymers during redox processes were studied by electrochemical quartz crystal microbalance and in situ spectroelectrochemical methods, to investigate the formation of the two polymers. In situ UV-visible spectroscopy evidenced the PCDK and PCD2K evolved into polarons in the near infrared region under applied potentials. Electrochromic behaviors showed that the PCDK film appeared reddish brown in neutral state and cyan or green in oxidized state while the PCD2K showed green to dark green from neutral to oxidized states. Potential switching between oxidized and neutral states of the two films revealed that maxima transmittance changes were 38.23% and 36.64% for the PCDK and PCD2K. Thermal degradation of the two polymers showed their robust stability that allows for the application in a wide temperature scale. (C) 2014 Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Electrochemistry |
| 研究领域[WOS] | Electrochemistry |
| 关键词[WOS] | TRIFLUORIDE DIETHYL ETHERATE ; CONDUCTING POLYMERS ; LOW BANDGAP ; ACCEPTOR ; ELECTRODE ; FILM |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000343626400014 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6321]  |
| 专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Wei,Gu, Chuantao,Wang, Jiuxing,et al. Electrochemistry and Near-infrared Electrochromism of Electropolymerized Polydithiophenes with beta, beta '-Positions Bridged by Carbonyl or Dicarbonyl Substitute[J]. ELECTROCHIMICA ACTA,2014,142:108-117. |
| APA | Liu, Wei,Gu, Chuantao,Wang, Jiuxing,Sun, Mingliang,&Yang, Renqiang.(2014).Electrochemistry and Near-infrared Electrochromism of Electropolymerized Polydithiophenes with beta, beta '-Positions Bridged by Carbonyl or Dicarbonyl Substitute.ELECTROCHIMICA ACTA,142,108-117. |
| MLA | Liu, Wei,et al."Electrochemistry and Near-infrared Electrochromism of Electropolymerized Polydithiophenes with beta, beta '-Positions Bridged by Carbonyl or Dicarbonyl Substitute".ELECTROCHIMICA ACTA 142(2014):108-117. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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