Effective regulation of the micro-structure of thick P3HT:PC71BM film by the incorporation of ethyl benzenecarboxylate in toluene solution
文献类型：期刊论文
| 作者 | Shen, Wenfei1; Xiao, Manjun2; Tang, Jianguo1; Wang, Xinzhi1; Chen, Weichao2 ; Yang, Renqiang2; Bao, Xichang2; Wang, Yao1; Jiao, Jiqing1; Huang, Linjun1
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| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:59页码:47451-47457 |
| 英文摘要 | In this work, ethyl benzenecarboxylate (EB) was creatively selected as the additive in a blend of poly(3-hexylthiophene)/phenyl-C71-butyric acid methyl ester (P3HT/PC71BM) in non-halogenated solvent toluene (TL). With the optimized incorporating concentration of EB (i.e. 2 vol%) in toluene, a great power conversion efficiency (PCE) enhancement of 4.11% was achieved without thermal annealing, whereas a maximum PCE of 4.82% with thermal annealing was achieved under the same conditions. According to our systematic characterization results, we could conclude that we successfully regulated the microstructures, including phase separation, the domain sizes of P3HT or PC71BM and the crystallinity of P3HT by incorporating 2 vol% EB in TL solution. The effectiveness of EB as a TL additive in P3HT/PC71BM can be interpreted based on its Hansen solubility parameters (HSPs) and its high boiling point. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | POLYMER SOLAR-CELLS ; POWER CONVERSION EFFICIENCY ; 25TH ANNIVERSARY ARTICLE ; MORPHOLOGY CONTROL ; SOLVENT ; POLY(3-HEXYLTHIOPHENE) ; PERFORMANCE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000355703700022 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6479]  |
| 专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
| 作者单位 | 1.Qingdao Univ, Growing Base State Key Lab, Inst Hybrid Mat, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 3.Colorado State Univ, Dept Chem & Biol Engn, Ft Collins, CO 80523 USA |
| 推荐引用方式 GB/T 7714 | Shen, Wenfei,Xiao, Manjun,Tang, Jianguo,et al. Effective regulation of the micro-structure of thick P3HT:PC71BM film by the incorporation of ethyl benzenecarboxylate in toluene solution[J]. RSC ADVANCES,2015,5(59):47451-47457. |
| APA | Shen, Wenfei.,Xiao, Manjun.,Tang, Jianguo.,Wang, Xinzhi.,Chen, Weichao.,...&Belfiore, Laurence A..(2015).Effective regulation of the micro-structure of thick P3HT:PC71BM film by the incorporation of ethyl benzenecarboxylate in toluene solution.RSC ADVANCES,5(59),47451-47457. |
| MLA | Shen, Wenfei,et al."Effective regulation of the micro-structure of thick P3HT:PC71BM film by the incorporation of ethyl benzenecarboxylate in toluene solution".RSC ADVANCES 5.59(2015):47451-47457. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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