Benzodithiophene-based two-dimensional polymers with extended conjugated thienyltriphenylamine substituents for high-efficiency polymer solar cells
文献类型：期刊论文
| 作者 | Fan, Qunping1; Liu, Yu1; Yang, Pingao1; Su, Wenyan1; Xiao, Manjun1; Chen, Jianhua1; Li, Min1; Wang, Xiangdong1; Wang, Yafei1; Tan, Hua1 |
| 刊名 | ORGANIC ELECTRONICS
 |
| 出版日期 | 2015-08-01 |
| 卷号 | 23页码:124-132 |
| 关键词 | Benzo[1 Extended conjugated side chain Two-dimensional Thienyltriphenylamine Polymer solar cells 2-b: 4 5-b ']dithiophene |
| 英文摘要 | Two novel donor-acceptor (D-A)-type two-dimensional (2-D) polymers of PTTPABDT-DTBT and PTTPABDT-DFDTBT were synthesized and characterized, in which extended conjugated side chained 4-thienyltriphenylamine benzo[1,2-b: 4,5-b'] dithiophene (TTPABDT) as the donor unit, thiophene (T) as the p-bridge, benzo[c][1,2,5] thiadiazole (BT) and 5,6-difluorobenzo[c][1,2,5] thiadiazole (DFBT) as the acceptor units. Due to the introduction of the extended conjugated side chained TTPA, polymers exhibited good thermal stabilities, broad absorption spectra and narrow optical band gaps. The hole mobility of 2.15 x 10(-4) cm(2) V-1 s(-1) was obtained in the PTTPABDT-DFDTBT/PC71BM blended film, which is two times higher than that of the PTTPABDT-DTBT/PC71BM blended film. Finally, the PTTPABDT-DFDTBT/PC71BM-based polymer solar cells presented the best power conversion efficiency (PCE) of 4.29% with a fill factor (FF) of 62.5%, while PTTPABDT-DTBT-based devices shown a PCE of 3.92% with a FF of 58.8%. The results indicate that the introduction of the extended conjugated TTPA side chain into the D-A-type 2-D polymers is an efficient approach to improve photovoltaic performances for its resulting polymers. (C) 2015 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| 类目[WOS] | Materials Science, Multidisciplinary ; Physics, Applied |
| 研究领域[WOS] | Materials Science ; Physics |
| 关键词[WOS] | POWER CONVERSION EFFICIENCY ; PHOTOVOLTAIC PERFORMANCE ; FLUORINATED BENZOTHIADIAZOLE ; SEMICONDUCTING POLYMERS ; MOLECULAR DESIGN ; COPOLYMERS ; LEVEL ; 1,2-B4,5-B' ; BITHIENYL ; IMPROVE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000354575700019 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/6485]  |
| 专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
| 作者单位 | 1.Xiangtan Univ, Coll Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Qunping,Liu, Yu,Yang, Pingao,et al. Benzodithiophene-based two-dimensional polymers with extended conjugated thienyltriphenylamine substituents for high-efficiency polymer solar cells[J]. ORGANIC ELECTRONICS,2015,23:124-132. |
| APA | Fan, Qunping.,Liu, Yu.,Yang, Pingao.,Su, Wenyan.,Xiao, Manjun.,...&Zhu, Weiguo.(2015).Benzodithiophene-based two-dimensional polymers with extended conjugated thienyltriphenylamine substituents for high-efficiency polymer solar cells.ORGANIC ELECTRONICS,23,124-132. |
| MLA | Fan, Qunping,et al."Benzodithiophene-based two-dimensional polymers with extended conjugated thienyltriphenylamine substituents for high-efficiency polymer solar cells".ORGANIC ELECTRONICS 23(2015):124-132. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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