A comparative study of Ag/Al2O3 and Cu/Al2O3 catalysts for the selective catalytic reduction of NO byC(3)H(6)
文献类型：期刊论文
| 作者 | He, H; Zhang, CB; Yu, YB |
| 刊名 | CATALYSIS TODAY
 |
| 出版日期 | 2004 |
| 卷号 | 90期号:2015-03-04页码:191-197 |
| 关键词 | enolic species selective catalytic reduction of NO (SCR of NO) in situ DRIFT'S reaction mechanism |
| 英文摘要 | The selective catalytic reduction of NOx with C3H6 (C3H6-SCR of NOx) was carried out in the presence of water vapor over various trace noble metal (Pt, Au and Pd) co-impregnated with Ag/Al2O3 catalysts. The Ag-Pd (0.01%)/Al2O3 shows a higher NOx, conversion than Ag/Al2O3 does, especially at temperatures ranging from 300 to 500degreesC. However, the additions of An and Pt to Ag/Al2O3 only resulted in a decrease of activity for the C3H6-SCR of NOx. In situ DRIFTS spectra suggests that the presence of trace Pd (0.01%) catalyzed the formation of an enolic species which was converted from C3H6, whereas the presence of Pt and Au did not show this effect. The surface enolic species is very active towards NO2 and NO3-, resulting in the formation of an NCO species which is the key reaction intermediate in the selective catalytic reduction of NOx (C) 2004 Elsevier B.V. All rights reserved. |
| 研究领域[WOS] | Chemistry ; Engineering |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23404]  |
| 专题 | 生态环境研究中心_大气环境科学实验室 |
| 推荐引用方式 GB/T 7714 | He, H,Zhang, CB,Yu, YB. A comparative study of Ag/Al2O3 and Cu/Al2O3 catalysts for the selective catalytic reduction of NO byC(3)H(6)[J]. CATALYSIS TODAY,2004,90(2015-03-04):191-197. |
| APA | He, H,Zhang, CB,&Yu, YB.(2004).A comparative study of Ag/Al2O3 and Cu/Al2O3 catalysts for the selective catalytic reduction of NO byC(3)H(6).CATALYSIS TODAY,90(2015-03-04),191-197. |
| MLA | He, H,et al."A comparative study of Ag/Al2O3 and Cu/Al2O3 catalysts for the selective catalytic reduction of NO byC(3)H(6)".CATALYSIS TODAY 90.2015-03-04(2004):191-197. |
入库方式： OAI收割
来源：生态环境研究中心
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。