Selective catalytic reduction of NOx in the presence of excess oxygen - II. SCR of NOx with oxo-organic compounds over Ag/Al2O3
文献类型：期刊论文
| 作者 | He, Y; Yu, YB; Liu, FS; Zhang, RD; Zhang, CB; Wang, J |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2004 |
| 卷号 | 25期号:6页码:460-466 |
| 关键词 | silver alumina supported catalyst nitrogen oxide selective catalytic reduction oxo-organic compound ethanol |
| 英文摘要 | The selective catalytic reduction (SCR) of NO with propylene was investigated over Cu/Al2O3 catalyst by using fixed-bed reactor and in situ FTIR and compared with Ag/Al2O3 which has a relative high activity in C3H6-SCR of NO. The highest conversion of NO is only 40% at about 650 K, when the catalyst was exposed to a gas mixture of NO/C3H6/O-2/N-2 = 0- 08%/0. 171 4% /10% /balance with W/F= 0. 018 g (.) s/mL. Surface R-NO2 and R-ONO species, which were observed on Ag/Al2O3 catalyst as the precursor of -NCO species, can hardly be found on Cu/Al2O3 catalyst surface in FTIR spectra under the same condition. This results in the low activity of Cu/Al2O3 catalyst for NO reduction. Through dynamic FTIR experiment, it was found that NOT species, which are dominant surface species over Cu/Al2O3 catalyst, have a low activity with C3H6, so that the reaction producing R-NO2 and,R-ONO is very difficult to take place. |
| 研究领域[WOS] | Chemistry |
| WOS记录号 | WOS:000222531200009 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23415]  |
| 专题 | 生态环境研究中心_大气环境科学实验室 |
| 推荐引用方式 GB/T 7714 | He, Y,Yu, YB,Liu, FS,et al. Selective catalytic reduction of NOx in the presence of excess oxygen - II. SCR of NOx with oxo-organic compounds over Ag/Al2O3[J]. CHINESE JOURNAL OF CATALYSIS,2004,25(6):460-466. |
| APA | He, Y,Yu, YB,Liu, FS,Zhang, RD,Zhang, CB,&Wang, J.(2004).Selective catalytic reduction of NOx in the presence of excess oxygen - II. SCR of NOx with oxo-organic compounds over Ag/Al2O3.CHINESE JOURNAL OF CATALYSIS,25(6),460-466. |
| MLA | He, Y,et al."Selective catalytic reduction of NOx in the presence of excess oxygen - II. SCR of NOx with oxo-organic compounds over Ag/Al2O3".CHINESE JOURNAL OF CATALYSIS 25.6(2004):460-466. |
入库方式： OAI收割
来源：生态环境研究中心
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