中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Selective catalytic reduction of NO in the presence of excess oxygen I center dot SCR of NO with C3H6 over Ag/Al2O3

文献类型:期刊论文

作者He, H; Zhang, RD; Yu, YB; Liu, JF
刊名CHINESE JOURNAL OF CATALYSIS
出版日期2003
卷号24期号:10页码:788-794
关键词silver alumina supported catalyst nitrogen oxide selective catalytic reduction propene
英文摘要The selective catalytic reduction (SCR) of NO with C3H6 over Ag/Al2O3 in excess oxygen was studied. The Ag particles could evenly be dispersed on the surface of Al2O3 with an optimal Ag loading of 4%similar to6% and an average size of 15 nm. The NO conversion over 4%Ag/Al2O3 catalyst was above 90% under the conditions of GHSV = 50 000 h(-1) and theta = 430 similar to 550 degreesC. Organic nitro-compounds (R-ONO, R-NO2) and nitrogen dioxide formed during the SCR reaction resulted in the difference between NO and NO, conversion. The optimal NO reduction reactivity over Ag/Al2O3 was achieved in the presence of 7% O-2. The NO conversion decreased with the introduction of water, compared with the condition in the absence of water, because the formation of R-ONO and R-NO2 and subsequently their decomposition into Ag-NCO and Al-NCO on the surface of Ag/Al2O3 were suppressed.
研究领域[WOS]Chemistry ; Engineering
WOS记录号WOS:000186595800016
源URL[http://ir.rcees.ac.cn/handle/311016/23659]  
专题生态环境研究中心_大气环境科学实验室
推荐引用方式
GB/T 7714
He, H,Zhang, RD,Yu, YB,et al. Selective catalytic reduction of NO in the presence of excess oxygen I center dot SCR of NO with C3H6 over Ag/Al2O3[J]. CHINESE JOURNAL OF CATALYSIS,2003,24(10):788-794.
APA He, H,Zhang, RD,Yu, YB,&Liu, JF.(2003).Selective catalytic reduction of NO in the presence of excess oxygen I center dot SCR of NO with C3H6 over Ag/Al2O3.CHINESE JOURNAL OF CATALYSIS,24(10),788-794.
MLA He, H,et al."Selective catalytic reduction of NO in the presence of excess oxygen I center dot SCR of NO with C3H6 over Ag/Al2O3".CHINESE JOURNAL OF CATALYSIS 24.10(2003):788-794.

入库方式: OAI收割

来源:生态环境研究中心

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