Effect Of SO2 on the performance of Ag-Pd/Al2O3 for the selective catalytic reduction of NOx with C2H5OH
文献类型:期刊论文
作者 | Xie Shu-xia; Yu Yun-bo; Wang Jin; He Hong |
刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
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出版日期 | 2006 |
卷号 | 18期号:5页码:973-978 |
关键词 | sulphate SCR nitrate enolic species isocyanate reaction mechanism |
英文摘要 | The influence of SO, on the performance of Ag-Pd/Al2O3 for the selective catalytic reduction (SCR) of NOx with C2H5OH was investigated experimentally. The activity test results suggest that Ag-Pd/Al2O3 shows a small activity loss in the presence Of SO2 when using C2H5OH as a reductant. In situ DRIFTS spectra show that the activity loss originates from the formation of surface sulphate species on the Ag-Pd/Al2O3. The surface sulphate species formation inhibits the formation of nitrate, whereas hardly changes the partial oxidation Of C2H5OH. Compared with the NOx reduction by C3H6 an obvious suppression of the surface sulphate species formation was observed by DRIFTS experiment when using C2H5OH as a reductant. This phenomenon reveals the better catalytic performance and strong SO2 tolerance ofAg-Pd/Al2O3-C2H5OH system. |
WOS记录号 | WOS:000240445400024 |
源URL | [http://ir.rcees.ac.cn/handle/311016/22873] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Xie Shu-xia,Yu Yun-bo,Wang Jin,et al. Effect Of SO2 on the performance of Ag-Pd/Al2O3 for the selective catalytic reduction of NOx with C2H5OH[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2006,18(5):973-978. |
APA | Xie Shu-xia,Yu Yun-bo,Wang Jin,&He Hong.(2006).Effect Of SO2 on the performance of Ag-Pd/Al2O3 for the selective catalytic reduction of NOx with C2H5OH.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,18(5),973-978. |
MLA | Xie Shu-xia,et al."Effect Of SO2 on the performance of Ag-Pd/Al2O3 for the selective catalytic reduction of NOx with C2H5OH".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 18.5(2006):973-978. |
入库方式: OAI收割
来源:生态环境研究中心
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