中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Selective determination of bisphenol A (BPA) in water by a reversible fluorescence sensor using pyrene/dimethyl beta-cyclodextrin complex

文献类型:期刊论文

作者Wang, X; Zeng, HL; Zhao, LX; Lin, JM
刊名ANALYTICA CHIMICA ACTA
出版日期2006
卷号556期号:2页码:313-318
关键词chemical sensor dimethyl beta-cyclodextrin pyrene bisphenol A competitive complexation
英文摘要A bifurcated optical fiberchemical sensor for continuous monitoring of bisphenol A (BPA) has been proposed based on the fluorescence quenching (lambda(ex)/lambda(em) = 286/390 nm) of pyrene/dimethyl beta-cyclodextrin (HDM-beta-CD) supramolecular complex immobilized in a plasticized poly(vinyl chloride) (PVC) membrane, in which pyrene served as a sensitive fluorescence indicator probe. The decrease of the fluorescence intensity of pyrene/HDM-beta-CD complex upon the addition of BPA was attributed to the displacement of pyrene by BPA, which has been utilized as the basis of the fabrication of a BPA-sensitive fluorescence sensor. The response mechanism of the sensor was discussed in detail. The sensor exhibited a dynamic detection range from 7.90 x 10(-8) to 1.66 x 10(-5) mol L-1 with a detection limit of 7.00 x 10(-8) mol L-1, and showed excellent reproducibility, reversibility, selectivity, and lifetime. The proposed sensor was successfully used for the determination of BPA in water samples and landfill leachate. (c) 2005 Elsevier B.V. All rights reserved.
WOS记录号WOS:000234729700009
源URL[http://ir.rcees.ac.cn/handle/311016/22922]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式
GB/T 7714
Wang, X,Zeng, HL,Zhao, LX,et al. Selective determination of bisphenol A (BPA) in water by a reversible fluorescence sensor using pyrene/dimethyl beta-cyclodextrin complex[J]. ANALYTICA CHIMICA ACTA,2006,556(2):313-318.
APA Wang, X,Zeng, HL,Zhao, LX,&Lin, JM.(2006).Selective determination of bisphenol A (BPA) in water by a reversible fluorescence sensor using pyrene/dimethyl beta-cyclodextrin complex.ANALYTICA CHIMICA ACTA,556(2),313-318.
MLA Wang, X,et al."Selective determination of bisphenol A (BPA) in water by a reversible fluorescence sensor using pyrene/dimethyl beta-cyclodextrin complex".ANALYTICA CHIMICA ACTA 556.2(2006):313-318.

入库方式: OAI收割

来源:生态环境研究中心

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