Separation of organomercury species using nonaqueous capillary electrophoresis coupled with sample stacking and electrokinetic injection techniques
文献类型:期刊论文
作者 | Peng, Zhen-Lei; Song, Guanqun; Zhao, Lixia; Lin, Jin-Ming |
刊名 | CHROMATOGRAPHIA
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出版日期 | 2006 |
卷号 | 64期号:2015-05-06页码:281-285 |
关键词 | capillary electrophoresis electrokinetic injection sample stacking organomercury |
英文摘要 | A nonaqueous capillary electrophoresis (NACE) method, 30 mM ammonium acetate in methanol as background electrolyte (BGE), was developed for separation of the organomercury species without complexing reagents. The effects of different solutes and solvents in BGE were studied. Three species of organomercury, methylmercury, ethylmercury and phenylmercury, were separated well and all the number of theoretical plates were over 10(6). The present NACE method was also coupled with sample stacking and electrokinetic injection techniques to enhance the detection sensitivity. Under the optimum conditions, the limit of detection (S/N = 3) is 18 ng mL(-1) and the linear relation range from 40 to 750 ng mL(-1) were obtained for methylmercury. |
WOS记录号 | WOS:000241222200008 |
源URL | [http://ir.rcees.ac.cn/handle/311016/22925] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Peng, Zhen-Lei,Song, Guanqun,Zhao, Lixia,et al. Separation of organomercury species using nonaqueous capillary electrophoresis coupled with sample stacking and electrokinetic injection techniques[J]. CHROMATOGRAPHIA,2006,64(2015-05-06):281-285. |
APA | Peng, Zhen-Lei,Song, Guanqun,Zhao, Lixia,&Lin, Jin-Ming.(2006).Separation of organomercury species using nonaqueous capillary electrophoresis coupled with sample stacking and electrokinetic injection techniques.CHROMATOGRAPHIA,64(2015-05-06),281-285. |
MLA | Peng, Zhen-Lei,et al."Separation of organomercury species using nonaqueous capillary electrophoresis coupled with sample stacking and electrokinetic injection techniques".CHROMATOGRAPHIA 64.2015-05-06(2006):281-285. |
入库方式: OAI收割
来源:生态环境研究中心
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