Separation of transition metals in nonaqueous media with capillary electrophoresis
文献类型：期刊论文
| 作者 | Qu, F; Lin, JM |
| 刊名 | JOURNAL OF CHROMATOGRAPHY A
 |
| 出版日期 | 2005 |
| 卷号 | 1068期号:1页码:169-174 |
| 关键词 | nonaqueous capillary electrophoresis transition metals organic acids |
| 英文摘要 | The separation of transition metal Ni-,(2+) Cu2+, Co2+, Zn2+, Cd2+ and Fe3+ in methanol was investigated by using different types of organic acids as complexing agents. In pure methanol, the weaker and simpler acetic, propionic, butyric and valeric acids could enhance metal ions selectivity by increasing acid concentration and metal ions could be separated with high efficiency. However, hydroxycarboxylic acids obviously made separation efficiency worse. The effect of mixed organic acids, mixture solvent (methanol-acetonitrile, methanol-water) on metal ions separation was discussed further. The advantages of using nonaqueous solvent over aqueous for metal ions separation were shown finally. (c) 2004 Elsevier B.V. All rights reserved. |
| 学科主题 | Biochemistry & Molecular Biology; Chemistry |
| 研究领域[WOS] | Biochemistry & Molecular Biology ; Chemistry |
| WOS记录号 | WOS:000227926000016 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23227]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Qu, F,Lin, JM. Separation of transition metals in nonaqueous media with capillary electrophoresis[J]. JOURNAL OF CHROMATOGRAPHY A,2005,1068(1):169-174. |
| APA | Qu, F,&Lin, JM.(2005).Separation of transition metals in nonaqueous media with capillary electrophoresis.JOURNAL OF CHROMATOGRAPHY A,1068(1),169-174. |
| MLA | Qu, F,et al."Separation of transition metals in nonaqueous media with capillary electrophoresis".JOURNAL OF CHROMATOGRAPHY A 1068.1(2005):169-174. |
入库方式： OAI收割
来源：生态环境研究中心
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