中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synergistic effect of palladium and oxygen vacancies in the Pd/perovskite catalysts synthesized by the spc method

文献类型:期刊论文

作者Zhou, KB; Chen, HD; Tian, Q; Zhu, BW; Shen, DX; Xu, XB
刊名JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
出版日期2005
卷号17期号:1页码:19-24
关键词Pd perovskite oxygen vacancies adsorbed oxygen spc method CO oxidation
英文摘要A series of oxygen-deficient perovskite-supported palladium catalysts were prepared by the "solid phase crystallization" (spc) method and investigated with XRD, TPR, TPD, TEM, XPS, BET analysis and CO oxidation. It was found that Pd/perovskite catalysts synthesized by the spc method were more active for CO oxidation than the calcined LaCo0.95 Pd0.05O3 , where Pd dispersed in the solid solution. H-2-reducing treatment in the spc method could yield not only high-dispersed fine Pd particles on the perovskite surface but also oxygen-deficient structure. In these perovskite-supported Pd catalysts, oxygen vacancies adsorbed, activated and supplied oxygen to the active Pd sites, where the oxidation occurred with adsorbed CO. The high activities were due to the cooperative action of Pd and oxygen vacancies.
学科主题Environmental Sciences & Ecology
研究领域[WOS]Environmental Sciences & Ecology
WOS记录号WOS:000226147000004
源URL[http://ir.rcees.ac.cn/handle/311016/23239]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
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GB/T 7714
Zhou, KB,Chen, HD,Tian, Q,et al. Synergistic effect of palladium and oxygen vacancies in the Pd/perovskite catalysts synthesized by the spc method[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2005,17(1):19-24.
APA Zhou, KB,Chen, HD,Tian, Q,Zhu, BW,Shen, DX,&Xu, XB.(2005).Synergistic effect of palladium and oxygen vacancies in the Pd/perovskite catalysts synthesized by the spc method.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,17(1),19-24.
MLA Zhou, KB,et al."Synergistic effect of palladium and oxygen vacancies in the Pd/perovskite catalysts synthesized by the spc method".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 17.1(2005):19-24.

入库方式: OAI收割

来源:生态环境研究中心

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