中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Separation of Cr(III) and Cr(VI) in river and reservoir water with 8-hydroxyquinoline immobilized polyacrylonitrile fiber for determination by inductively coupled plasma mass spectrometry

文献类型:期刊论文

作者Wen, B; Shan, XQ; Lian, J
刊名TALANTA
出版日期2002
卷号56期号:4页码:681-687
关键词8-hydroxyquinoline immobilized polyacrylonitrile fiber chromium(III) chromium(VI) inductively coupled plasma mass spectrometry river and reservoir water
英文摘要A rapid and simple method has been developed for the separation of chromium (III) and Cr(VI) species in river and reservoir water. Chromium (III) can be chelated with 8-hydroxyquinoline immobilized polyacrylonitrile (PAN) fiber, whereas Cr(VI) cannot. Chelated Cr(III) can be eluted with 2 mol l(-1) HCl-0.1 mol l(-1) HNO3. Cr(VI) in the filtrate and Cr(III) in the eluant were determined by inductively coupled plasma mass spectrometry. The effect of pH, sample flow rate, eluant type and its volume on the concentration effectiveness of Cr(III) was investigated. The recommended method has been applied for the separation and determination of Cr(III) and Cr(VI) in river and reservoir water. The results indicated that the recovery of each individual Cr species ranged from 96 to 107% and the R.S.D. were found to be <10% at the level of ng ml(-1). The effect of HNO3 added in the sampling procedure was also evaluated. (C) 2002 Elsevier Science B.V. All rights reserved.
研究领域[WOS]Chemistry
WOS记录号WOS:000174696300011
源URL[http://ir.rcees.ac.cn/handle/311016/23893]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式
GB/T 7714
Wen, B,Shan, XQ,Lian, J. Separation of Cr(III) and Cr(VI) in river and reservoir water with 8-hydroxyquinoline immobilized polyacrylonitrile fiber for determination by inductively coupled plasma mass spectrometry[J]. TALANTA,2002,56(4):681-687.
APA Wen, B,Shan, XQ,&Lian, J.(2002).Separation of Cr(III) and Cr(VI) in river and reservoir water with 8-hydroxyquinoline immobilized polyacrylonitrile fiber for determination by inductively coupled plasma mass spectrometry.TALANTA,56(4),681-687.
MLA Wen, B,et al."Separation of Cr(III) and Cr(VI) in river and reservoir water with 8-hydroxyquinoline immobilized polyacrylonitrile fiber for determination by inductively coupled plasma mass spectrometry".TALANTA 56.4(2002):681-687.

入库方式: OAI收割

来源:生态环境研究中心

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