Synthesis of oligosaccharide derivatives related to those from sanqi, a Chinese herbal medicine from Panax notoginseng
文献类型:期刊论文
作者 | Yang, F; Du, YG |
刊名 | CARBOHYDRATE RESEARCH
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出版日期 | 2002 |
卷号 | 337期号:6页码:485-491 |
关键词 | natural products neighboring-group effects stereoselectivity glycosylations oligosaccharide |
英文摘要 | Oligosaccharide derivatives from sanqi, a Chinese herbal medicine derived from Panax notoginseng, methyl beta-D-galactopyranosyl-(1 --> 3)-[alpha-L-arabinofuranosyl-(1 --> 6)]-alpha-D-galactopyranoside, diosgenyl beta-D-galactopyranosyl-(1 --> 3)-[alpha-L-arabinofuranosyl- --> 6)]-alpha-D-galactopyranoside, and methyl beta-D-galactopyranosyl-(1 --> 3)-[alpha-L-arabinofuranosyl-(1 --> --> 6)]-alpha-D-galactopyranosyl-(1 --> 4)-beta-D-galactopyranosyl-(1 --> 3)-[alpha-L-arabinofuranosyl-(1 --> 6)]-alpha-D-galactopyrano side, were synthesized under standard glycosylation conditions. An unexpected alpha-(1 --> 4) linkage was formed predominantly in the presence of neighboring participation group during regioselective synthesis of hexasaccharide via 3 + 3 strategy. (C) 2002 Elsevier Science Ltd. All rights reserved. |
研究领域[WOS] | Biochemistry & Molecular Biology ; Chemistry |
WOS记录号 | WOS:000174555900002 |
源URL | [http://ir.rcees.ac.cn/handle/311016/23900] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Yang, F,Du, YG. Synthesis of oligosaccharide derivatives related to those from sanqi, a Chinese herbal medicine from Panax notoginseng[J]. CARBOHYDRATE RESEARCH,2002,337(6):485-491. |
APA | Yang, F,&Du, YG.(2002).Synthesis of oligosaccharide derivatives related to those from sanqi, a Chinese herbal medicine from Panax notoginseng.CARBOHYDRATE RESEARCH,337(6),485-491. |
MLA | Yang, F,et al."Synthesis of oligosaccharide derivatives related to those from sanqi, a Chinese herbal medicine from Panax notoginseng".CARBOHYDRATE RESEARCH 337.6(2002):485-491. |
入库方式: OAI收割
来源:生态环境研究中心
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