Direct Grignard pentylation of organotin-contaminated lard samples followed by capillary gas chromatography with flame photometric detection
文献类型：期刊论文
| 作者 | Jiang, GB; Zhou, QF |
| 刊名 | JOURNAL OF CHROMATOGRAPHY A
 |
| 出版日期 | 2000 |
| 卷号 | 886期号:2015-01-02页码:197-205 |
| 关键词 | Grignard pentylation lard organotin compounds |
| 英文摘要 | During a recent investigation of the organotin-contaminated lard samples, a simple method was developed by direct Grignard pentylation of lard samples and capillary gas chromatography with flame photometric detection using quartz surface-induced tin emission. Using HP-I capillary column with temperature programming and FPD detector, pentylated tri-, di-, monometyltin, dioctyltin and Sn(IV) can be base-line separated and detected within 20 min. The analysis of pentylated tin compounds by GC-MS confirmed the existence of methyltins and inorganic tin in lard samples, which was agreeable with the results obtained by GC-FPD. The content of organotin compounds was calculated by internal standard method in which methyltripropyltin (MeSnPr3) acted as internal standard. The results showed that these samples were heavily contaminated with mg/g levers of dimethyltin, mu g/g levers of tri- and monomethyltin. Among them, one sample contained mg/g level of dioctyltin and one contained a little of inorganic form of Sn(IV). The recoveries of tri-, di- and monomethyltin were 95.7%, 105.5% and 105.7%, respectively. (C) 2000 Elsevier Science B.V. All rights reserved. |
| WOS记录号 | WOS:000088189600018 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/24130]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Jiang, GB,Zhou, QF. Direct Grignard pentylation of organotin-contaminated lard samples followed by capillary gas chromatography with flame photometric detection[J]. JOURNAL OF CHROMATOGRAPHY A,2000,886(2015-01-02):197-205. |
| APA | Jiang, GB,&Zhou, QF.(2000).Direct Grignard pentylation of organotin-contaminated lard samples followed by capillary gas chromatography with flame photometric detection.JOURNAL OF CHROMATOGRAPHY A,886(2015-01-02),197-205. |
| MLA | Jiang, GB,et al."Direct Grignard pentylation of organotin-contaminated lard samples followed by capillary gas chromatography with flame photometric detection".JOURNAL OF CHROMATOGRAPHY A 886.2015-01-02(2000):197-205. |
入库方式： OAI收割
来源：生态环境研究中心
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