Determination of selenium in biological tissue samples rich in phosphorus using electrothermal atomization with Zeeman-effect background correction and (NH4)(3)RhCl6 plus citric acid as a mixed chemical modifier
文献类型:期刊论文
作者 | Li, M; Ni, ZM; Rao, Z |
刊名 | SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY |
出版日期 | 1998 |
卷号 | 53期号:10页码:1381-1389 |
关键词 | Se biological tissue electrothermal atomic absorption spectrometry rhodium modifier Zeeman background correction phosphate interference |
英文摘要 | Spectral interferences from phosphorus on the determination of selenium in biological tissue materials were not observed when a Zeeman-effect background correction was used with rhodium as a chemical modifier. A suppression effect on the selenium signal resulted when the concentration of phosphorus present was greater than 1.0 mg ml(-1). Rhodium was found to be more effective than palladium in overcoming the phosphate: interference. Analytical procedures for the direct determination of trace selenium in standard reference materials by graphite furnace atomic absorption spectrometry following sample dissolution in nitric acid and hydrogen peroxide using a microwave oven has been described. The results obtained agreed favourably with the certified values. (C) 1998 Elsevier Science B.V. All rights reserved. |
研究领域[WOS] | Spectroscopy |
公开日期 | 2015-12-24 |
源URL | [http://ir.rcees.ac.cn/handle/311016/24275] |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Li, M,Ni, ZM,Rao, Z. Determination of selenium in biological tissue samples rich in phosphorus using electrothermal atomization with Zeeman-effect background correction and (NH4)(3)RhCl6 plus citric acid as a mixed chemical modifier[J]. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY,1998,53(10):1381-1389. |
APA | Li, M,Ni, ZM,&Rao, Z.(1998).Determination of selenium in biological tissue samples rich in phosphorus using electrothermal atomization with Zeeman-effect background correction and (NH4)(3)RhCl6 plus citric acid as a mixed chemical modifier.SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY,53(10),1381-1389. |
MLA | Li, M,et al."Determination of selenium in biological tissue samples rich in phosphorus using electrothermal atomization with Zeeman-effect background correction and (NH4)(3)RhCl6 plus citric acid as a mixed chemical modifier".SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY 53.10(1998):1381-1389. |
入库方式: OAI收割
来源:生态环境研究中心
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