中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Determination of selenium in biological tissue samples rich in phosphorus using electrothermal atomization with Zeeman-effect background correction and (NH4)(3)RhCl6 plus citric acid as a mixed chemical modifier

文献类型:期刊论文

作者Li, M; Ni, ZM; Rao, Z
刊名SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
出版日期1998
卷号53期号:10页码:1381-1389
关键词Se biological tissue electrothermal atomic absorption spectrometry rhodium modifier Zeeman background correction phosphate interference
英文摘要Spectral interferences from phosphorus on the determination of selenium in biological tissue materials were not observed when a Zeeman-effect background correction was used with rhodium as a chemical modifier. A suppression effect on the selenium signal resulted when the concentration of phosphorus present was greater than 1.0 mg ml(-1). Rhodium was found to be more effective than palladium in overcoming the phosphate: interference. Analytical procedures for the direct determination of trace selenium in standard reference materials by graphite furnace atomic absorption spectrometry following sample dissolution in nitric acid and hydrogen peroxide using a microwave oven has been described. The results obtained agreed favourably with the certified values. (C) 1998 Elsevier Science B.V. All rights reserved.
研究领域[WOS]Spectroscopy
公开日期2015-12-24
源URL[http://ir.rcees.ac.cn/handle/311016/24275]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式
GB/T 7714
Li, M,Ni, ZM,Rao, Z. Determination of selenium in biological tissue samples rich in phosphorus using electrothermal atomization with Zeeman-effect background correction and (NH4)(3)RhCl6 plus citric acid as a mixed chemical modifier[J]. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY,1998,53(10):1381-1389.
APA Li, M,Ni, ZM,&Rao, Z.(1998).Determination of selenium in biological tissue samples rich in phosphorus using electrothermal atomization with Zeeman-effect background correction and (NH4)(3)RhCl6 plus citric acid as a mixed chemical modifier.SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY,53(10),1381-1389.
MLA Li, M,et al."Determination of selenium in biological tissue samples rich in phosphorus using electrothermal atomization with Zeeman-effect background correction and (NH4)(3)RhCl6 plus citric acid as a mixed chemical modifier".SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY 53.10(1998):1381-1389.

入库方式: OAI收割

来源:生态环境研究中心

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