Atomization of Cu, Ag, Ni and In at constant temperature from tungsten probe surface
文献类型：期刊论文
| 作者 | Liang, YZ; Ni, ZM; Yan, XP |
| 刊名 | CHEMIA ANALITYCZNA
 |
| 出版日期 | 1996 |
| 卷号 | 41期号:4页码:601-613 |
| 关键词 | atomization of Cu tungsten probe activation energy Ag Ni and In |
| 英文摘要 | The kinetic order and activation energy of Cu, Ag, Ni and In for atom formation under isothermal condition in a graphite furnace have been determined by means of a newly developed method. A 2/3 order kinetic release of Cu indicates that the analyte desorbs from the surface of microdroplets on the probe with desorption energy of 193 +/- 24 kJ mol(-1). For Ag and In a fractional order of near 1/2 with E(a) values of 248 +/- 5 kJ mol(-1) and 123 +/- 8 kJ mol(-1), respectively, was obtained which implies the release of free Ag or In atoms from the interface of 2-D islands. As to Ni, a first-order kinetic process was observed with E(a) value of 297 +/- 6 kJ mol(-1), which suggests that the analyte desorbs from tungsten probe surface as highly dispersed atoms. The activation energy may represent the nickel-tungsten interaction energy. |
| 研究领域[WOS] | Chemistry |
| WOS记录号 | WOS:A1996VF01500010 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/24418]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Liang, YZ,Ni, ZM,Yan, XP. Atomization of Cu, Ag, Ni and In at constant temperature from tungsten probe surface[J]. CHEMIA ANALITYCZNA,1996,41(4):601-613. |
| APA | Liang, YZ,Ni, ZM,&Yan, XP.(1996).Atomization of Cu, Ag, Ni and In at constant temperature from tungsten probe surface.CHEMIA ANALITYCZNA,41(4),601-613. |
| MLA | Liang, YZ,et al."Atomization of Cu, Ag, Ni and In at constant temperature from tungsten probe surface".CHEMIA ANALITYCZNA 41.4(1996):601-613. |
入库方式： OAI收割
来源：生态环境研究中心
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