Influence of Cu-substituted hydrotalcite precursors and derived oxides
文献类型:期刊论文
作者 | Yu, JJ; Jiang, Z; Kang, SF; Hao, ZP; Hu, C |
刊名 | CHINESE JOURNAL OF CHEMICAL PHYSICS
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出版日期 | 2005 |
卷号 | 18期号:2页码:251-256 |
关键词 | hydrotalcite precursors composite oxides structure characterization |
英文摘要 | The coprecipitation method was used to prepare a series of different oxides (CuO: 0, 5%, 10%, 15%, 20%, 30% and 40%) derived from Cu substituted Mg/Al-mixed anionic clay precursors (hydrotalcites) at the ratio of M2+/M3+ = 3. In order to study influences of Cu and Mg content upon the performance of these materials, such characterization techniques as X-ray diffraction, thermogravimetrical analysis, differential scanning calorimetry, temperature programmed reaction and Fourier transform infrared reflectance spectra, were used. The results showed that complete structure of hydrotalcite precursors could be formed when CuO ≤ 30%. When CuO ≥ 40%, Cu(OH)(2) phase appeared. Homogeneous composite oxides can be obtained by high temperature calcination at CuO ≤ 20%. When CuO > 20%, CuO phase was isolated. The content of Cu and Mg had significant influences on thermal stability of materials. The reduction ability of materials was related to calcination temperatures and material composition. |
学科主题 | Physics |
研究领域[WOS] | Physics |
WOS记录号 | WOS:000228910100020 |
源URL | [http://ir.rcees.ac.cn/handle/311016/23257] ![]() |
专题 | 生态环境研究中心_环境纳米材料实验室 |
推荐引用方式 GB/T 7714 | Yu, JJ,Jiang, Z,Kang, SF,et al. Influence of Cu-substituted hydrotalcite precursors and derived oxides[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2005,18(2):251-256. |
APA | Yu, JJ,Jiang, Z,Kang, SF,Hao, ZP,&Hu, C.(2005).Influence of Cu-substituted hydrotalcite precursors and derived oxides.CHINESE JOURNAL OF CHEMICAL PHYSICS,18(2),251-256. |
MLA | Yu, JJ,et al."Influence of Cu-substituted hydrotalcite precursors and derived oxides".CHINESE JOURNAL OF CHEMICAL PHYSICS 18.2(2005):251-256. |
入库方式: OAI收割
来源:生态环境研究中心
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