A cleaner two-step synthesis of high purity diallyldimethylammonium chloride monomers for flocculant preparation
文献类型：期刊论文
| 作者 | Tian, BH; Fan, B; Peng, XJ; Luan, ZK |
| 刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
 |
| 出版日期 | 2005 |
| 卷号 | 17期号:5页码:798-801 |
| 关键词 | diallyldimethylammonium chloride microwave irradiation flocculant cleaner process |
| 英文摘要 | In order to improve the flocculation efficiency of polydiallyldimethylammonium chloride( PDADMAC), high molecular weight PDADMAC should be prepared from high purity diallyldimethylammonium chloride( DADMAC) monomers. In this paper, a cleaner method with microwave irradiation and alkali solidification was proposed for preparing high pure DADMAC by selective heating under low temperature, and the prepared high purity DADMAC is characterized using FTIR and atomic absorption spectrometry. The new method provides a solution to the key technical problem of PDADMAC synthesis. Comparing with the conventional methods, the results showed that the advantages of the novel synthesis include: (a) high purity DADMAC is improved from 57% to 71%; (b) reaction time of tertiary amine preparation is shortened from 6 h to 7 min; (c) water instead of acetone was used as reaction medium; (d) toxic by-products, wastewater and waste gas are eliminated. Flocculant made from the synthesized high purity DADMAC monomers was proved more efficient in flocculation tests. |
| 学科主题 | Environmental Sciences & Ecology |
| 研究领域[WOS] | Environmental Sciences & Ecology |
| WOS记录号 | WOS:000231642900019 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23263]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Tian, BH,Fan, B,Peng, XJ,et al. A cleaner two-step synthesis of high purity diallyldimethylammonium chloride monomers for flocculant preparation[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2005,17(5):798-801. |
| APA | Tian, BH,Fan, B,Peng, XJ,&Luan, ZK.(2005).A cleaner two-step synthesis of high purity diallyldimethylammonium chloride monomers for flocculant preparation.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,17(5),798-801. |
| MLA | Tian, BH,et al."A cleaner two-step synthesis of high purity diallyldimethylammonium chloride monomers for flocculant preparation".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 17.5(2005):798-801. |
入库方式： OAI收割
来源：生态环境研究中心
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