The influence of Ca on hydrolysisand polymerization of aluminum and physicochemical characteristics of polyaluminum chloride
文献类型：期刊论文
| 作者 | Zhao, HZ; Luan, ZK; Jiang, ZP |
| 刊名 | CHINESE JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2004 |
| 卷号 | 20期号:9页码:1045-1049 |
| 关键词 | Al-13 species polyaluminum chloride containing Ca hydrolysis and polymerization aluminum species |
| 英文摘要 | The polyaluminum chloride containing Ca was prepared by adding Ca before and after the aluminium polymerization, respectively. The effects of Ca on the hydrolysis and polymerization of aluminum, the characteristic of aluminum species, the zeta potential and viscosity of PAC were also studied. The experimental results show that the introduction of Ca retards the formation of Al precipitates during the hydrolysis and polymerization of aluminum and increases the contents of Al-m and Al-13 in PAC. Aluminum species can complex with Ca to form heteronuclear hydroxo complexes, which decreases the chemical shifts of Al-m and Al-13 in NMR. The zeta potential and the viscosity of PAC increase with the rise of Ca/Al molar ratio. Comparing with adding Ca after the aluminium polymerization, there are much more Al-Ca heteronuclear hydroxo complexes formed by adding Ca before the polymerization, which leads to a more obvious influence of Ca/Al molar ratio on the zeta potential and the viscosity of PAC. |
| 研究领域[WOS] | Chemistry |
| WOS记录号 | WOS:000223713500008 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23549]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhao, HZ,Luan, ZK,Jiang, ZP. The influence of Ca on hydrolysisand polymerization of aluminum and physicochemical characteristics of polyaluminum chloride[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2004,20(9):1045-1049. |
| APA | Zhao, HZ,Luan, ZK,&Jiang, ZP.(2004).The influence of Ca on hydrolysisand polymerization of aluminum and physicochemical characteristics of polyaluminum chloride.CHINESE JOURNAL OF INORGANIC CHEMISTRY,20(9),1045-1049. |
| MLA | Zhao, HZ,et al."The influence of Ca on hydrolysisand polymerization of aluminum and physicochemical characteristics of polyaluminum chloride".CHINESE JOURNAL OF INORGANIC CHEMISTRY 20.9(2004):1045-1049. |
入库方式： OAI收割
来源：生态环境研究中心
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