Characteristics and formation of [AlO4Al12(OH)(24)(H2O)(12)](7+) in electrolysis process
文献类型：期刊论文
| 作者 | Liu, HJ; Qu, JH; Zhang, SJ; Hu, CZ |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 2002 |
| 卷号 | 45期号:5页码:515-520 |
| 关键词 | electrolysis process partially hydrolyzed aluminum solution Al-13 polymer size distribution Al-27 NMR spectroscopy dynamic light scattering |
| 英文摘要 | [AIO(4)Al(12)(OH)(24)(H2O)(12)](7+) (Al-13) formation in electrolysis process is studied. The results detected by Al-27 NMR spectroscopy show that high content of Al-13 polymer is formed in the partially hydrolyzed aluminum solution prepared by controlled electrolysis process. In the produced electrolyte of total Al concentration ([Al-T]) 2.0 mol L-1 with a basicity (B = OH/Al molar ratios) of 2.0, the content of Al-13 polymer is over 60% of total Al. Dynamic light scattering shows that the size distribution of the final electrolyte solutions ([Al-T] = 2.0 mol L-1) is trimodal with B = 2.0 and bimodal with B = 2.5. The aggregates of Al-13 complexes increase the particle size of partially hydrolyzed aluminum solution. |
| 研究领域[WOS] | Chemistry |
| WOS记录号 | WOS:000178162500011 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23921]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Liu, HJ,Qu, JH,Zhang, SJ,et al. Characteristics and formation of [AlO4Al12(OH)(24)(H2O)(12)](7+) in electrolysis process[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2002,45(5):515-520. |
| APA | Liu, HJ,Qu, JH,Zhang, SJ,&Hu, CZ.(2002).Characteristics and formation of [AlO4Al12(OH)(24)(H2O)(12)](7+) in electrolysis process.SCIENCE IN CHINA SERIES B-CHEMISTRY,45(5),515-520. |
| MLA | Liu, HJ,et al."Characteristics and formation of [AlO4Al12(OH)(24)(H2O)(12)](7+) in electrolysis process".SCIENCE IN CHINA SERIES B-CHEMISTRY 45.5(2002):515-520. |
入库方式： OAI收割
来源：生态环境研究中心
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