Determination of nonylphenol ethoxylates in the aquatic environment by normal phase liquid chromatography-electrospray mass spectrometry
文献类型：期刊论文
| 作者 | Shao, B; Hu, JY; Yang, M |
| 刊名 | JOURNAL OF CHROMATOGRAPHY A
 |
| 出版日期 | 2002 |
| 卷号 | 950期号:2015-01-02页码:167-174 |
| 关键词 | water analysis nonylphenol ethoxylates surfactants |
| 英文摘要 | A comprehensive analytical method based on normal-phase liquid chromatography-electrospray ionization mass spectrometry (NPLC-ESI-MS) has been established for determination of nonylphenol ethoxylates (NPEOs) in the aquatic environment. Extraction and cleanup of samples were performed on graphitized carbon black (GCB) solid-phase extraction cartridges. Complete separation between each individual NPEOs was achieved by combining a C-18 pre-column with a silica analytical column and using acetonitrile-water as eluent. Quantitative determination by LC-ESI-MS was achieved in the positive ionization (PI) mode at a ramped cone voltage for NPEOs using selected ion monitoring. Recoveries for NPEOs ranged between 91.9 and 117.5%, and the limits of detection varied between 0.5 and 2 ng/l for individual NPEOs with n longer than 2, and between 5 and 0.5 mug/l for NP1EO and NP2EO. This method was successfully applied to the investigation of residual NPEOs with n>2 in the Chongqing area of the Changjiang river. NPEOs with n ranging from 1 to 22 were found to vary between 0.1 and 2900 ng/l with a distribution depending on the depth of water. (C) 2002 Elsevier Science B V All rights reserved. |
| 研究领域[WOS] | Biochemistry & Molecular Biology ; Chemistry |
| WOS记录号 | WOS:000174786200017 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23924]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Shao, B,Hu, JY,Yang, M. Determination of nonylphenol ethoxylates in the aquatic environment by normal phase liquid chromatography-electrospray mass spectrometry[J]. JOURNAL OF CHROMATOGRAPHY A,2002,950(2015-01-02):167-174. |
| APA | Shao, B,Hu, JY,&Yang, M.(2002).Determination of nonylphenol ethoxylates in the aquatic environment by normal phase liquid chromatography-electrospray mass spectrometry.JOURNAL OF CHROMATOGRAPHY A,950(2015-01-02),167-174. |
| MLA | Shao, B,et al."Determination of nonylphenol ethoxylates in the aquatic environment by normal phase liquid chromatography-electrospray mass spectrometry".JOURNAL OF CHROMATOGRAPHY A 950.2015-01-02(2002):167-174. |
入库方式： OAI收割
来源：生态环境研究中心
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