Rhodium tin composite oxides co-catalyst for high efficient photocatalytic hydrogen evolution
文献类型：期刊论文
| 作者 | Li Z(李振)1,2; Kong C(孔超)1,2 ; Lu GX(吕功煊)1
|
| 刊名 | International Journal of Hydrogen Energy
 |
| 出版日期 | 2015 |
| 卷号 | 40期号:30页码:9061-9068 |
| 关键词 | Photocatalysis Visible light Hydrogen evolution Co-catalyst RhSnxOy Eosin Y sensitization |
| ISSN号 | 0360-3199 |
| 通讯作者 | 吕功煊 |
| 英文摘要 | In this work, we studied the modification of surface active site of Rh in RhSnxOy composite oxide co-catalyst by the addition of Sn for high efficient photocatalytic hydrogen evolution under visible light irradiation. The significant activity promotion was accomplished by the adjustment of Rh sites via Sn addition. After sensitized by Eosin Y (EY) dye, the RhSnxOy co-catalyst exhibited the apparent quantum efficiency (AQE) of 21.0% at 430 nm for hydrogen generation. Under optimized conditions, the highest hydrogen evolution rate of 1280.3 μmol h−1 (corresponding TON 64) over RhSnxOy co-catalyst was achieved, which was 8.3 times higher than that of Rh co-catalyst. Based on the XRD and XPS characterizations, Rh atom arrangement on the surface of RhSnxOy co-catalyst was confirmed. By adjusting Rh sites, it showed significantly different interaction between Rh atoms and Sn atoms, which led to more efficient excited charge separation and transfer from Rh atoms to Sn atoms with the amount of Sn increased, resulting in more effective photo-induced hydrogen generation. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the 973 and 863 Programs of Department of Sciences and Technology of China (2013CB632404;2012AA051501);the NSF of China (Grant No. 21173242;21433007) |
| 语种 | 英语 |
| WOS记录号 | WOS:000358811000006 |
| 源URL | [http://210.77.64.217/handle/362003/18540]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 10080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Z,Kong C,Lu GX. Rhodium tin composite oxides co-catalyst for high efficient photocatalytic hydrogen evolution[J]. International Journal of Hydrogen Energy,2015,40(30):9061-9068. |
| APA | Li Z,Kong C,&Lu GX.(2015).Rhodium tin composite oxides co-catalyst for high efficient photocatalytic hydrogen evolution.International Journal of Hydrogen Energy,40(30),9061-9068. |
| MLA | Li Z,et al."Rhodium tin composite oxides co-catalyst for high efficient photocatalytic hydrogen evolution".International Journal of Hydrogen Energy 40.30(2015):9061-9068. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。