Synthesis and Characterization of Cobalt Complexes with Radical Anionic alpha-Diimine Ligands
文献类型：期刊论文
| 作者 | Yang XJ(杨晓娟)1 ; Fan, Xiaohui1; Zhao YX(赵艳霞)1; Wang, Xuting1; Liu, Bin1; Su JH(苏吉虎)2; Dong QS(董青松)3; Xu, Maolin1; Wu B(吴彪)1
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| 刊名 | Organometallics
 |
| 出版日期 | 2013 |
| 卷号 | 32期号:23页码:6945-6949 |
| ISSN号 | 0276-7333 |
| 通讯作者 | 杨晓娟 |
| 英文摘要 | Three cobalt complexes, [LCo(mu-Cl)]2· THF · Et2O (1), [LCo(η6-toluene)] (2), and [LCo]2 (3), where L = [(2,6-iPr2C6H3)NC(Me)]2, have been synthesized from reduction of the dichloro cobalt precursor [LCoCl2] by sodium or potassium metal. Single-crystal X-ray diffraction analyses reveal that the complexes display novel structures with the singly reduced form (L·-) of the α-diimine ligand: the dichloro-bridged binuclear complex 1, the mononuclear 2 with an η6-coordinated toluene molecule, and the dimer 3 through Co-aryl interactions of two [LCo] units. The compounds were further characterized by EPR and magnetic studies. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Grant No. 21273170) |
| 语种 | 英语 |
| WOS记录号 | WOS:000328240200014 |
| 源URL | [http://210.77.64.217/handle/362003/18201]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.NW Univ Xian, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian 710069, Peoples R China 2.Univ Sci & Technol China, Dept Modern Phys, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang XJ,Fan, Xiaohui,Zhao YX,et al. Synthesis and Characterization of Cobalt Complexes with Radical Anionic alpha-Diimine Ligands[J]. Organometallics,2013,32(23):6945-6949. |
| APA | Yang XJ.,Fan, Xiaohui.,Zhao YX.,Wang, Xuting.,Liu, Bin.,...&Wu B.(2013).Synthesis and Characterization of Cobalt Complexes with Radical Anionic alpha-Diimine Ligands.Organometallics,32(23),6945-6949. |
| MLA | Yang XJ,et al."Synthesis and Characterization of Cobalt Complexes with Radical Anionic alpha-Diimine Ligands".Organometallics 32.23(2013):6945-6949. |
入库方式： OAI收割
来源：兰州化学物理研究所
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