Synthesis of Aryl Thiocyanates via Copper-Catalyzed Aerobic Oxidative Cross-Coupling between Arylboronic Acids and KSCN
文献类型：期刊论文
| 作者 | Sun N(孙楠)1; Zhang, Han1; Mo WM(莫卫民)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Hu XQ(胡信全)1,2 |
| 刊名 | SYNLETT
 |
| 出版日期 | 2013 |
| 卷号 | 24期号:11页码:1443-1447 |
| 关键词 | aryl thiocyanates arylboronic acids potassium thiocyanate copper acetate oxidative cross-coupling reaction |
| ISSN号 | 0936-5214 |
| 通讯作者 | 胡信全 |
| 英文摘要 | A new protocol for the preparation of aryl thiocyanates by the cross-coupling reaction of arylboronic acids with KSCN salt is described. The coupling reaction was catalyzed by 20 mol% of copper acetate in the presence of 2.0 equivalents 4-methylpyridine serving both as ligand and base under 0.2 MPa of molecular oxygen. A variety of arylboronic acids, including those with substituents at ortho position, were suitable under the reaction conditions. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the Major Project of Science and Technology Department of Zhejiang Province (No. 2010C11039);the Key Innovative Team Project of Zhejiang Province, China (No. 2009R50002) |
| 语种 | 英语 |
| WOS记录号 | WOS:000320576600021 |
| 源URL | [http://210.77.64.217/handle/362003/18246]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun N,Zhang, Han,Mo WM,et al. Synthesis of Aryl Thiocyanates via Copper-Catalyzed Aerobic Oxidative Cross-Coupling between Arylboronic Acids and KSCN[J]. SYNLETT,2013,24(11):1443-1447. |
| APA | Sun N,Zhang, Han,Mo WM,Hu BX,Shen ZL,&Hu XQ.(2013).Synthesis of Aryl Thiocyanates via Copper-Catalyzed Aerobic Oxidative Cross-Coupling between Arylboronic Acids and KSCN.SYNLETT,24(11),1443-1447. |
| MLA | Sun N,et al."Synthesis of Aryl Thiocyanates via Copper-Catalyzed Aerobic Oxidative Cross-Coupling between Arylboronic Acids and KSCN".SYNLETT 24.11(2013):1443-1447. |
入库方式： OAI收割
来源：兰州化学物理研究所
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