(EtO)(3)SiH-Promoted Palladium-Catalyzed Isomerization of Olefins: Convenient Synthesis of Internal Alkenes from Terminal Alkenes
文献类型：期刊论文
| 作者 | Bai XF(柏惺峰)1,2,3; Song, Tao1; Deng WH(邓文慧)1; Wei, Yun-Long1; Li L(李莉)1; Xia CG(夏春谷)2,3 ; Xu LW(徐利文)1,2,3
|
| 刊名 | SYNLETT
 |
| 出版日期 | 2014 |
| 卷号 | 25期号:3页码:417-422 |
| 关键词 | olefin palladium isomerization cassumunin organosilicon |
| ISSN号 | 0936-5214 |
| 通讯作者 | 李莉 ; 徐利文 |
| 英文摘要 | The catalytic activity of an in situ forming palladium catalyst system generated from PdCl2(PPh3)2 and hydrosilane [(EtO)3SiH] was revealed in the one-carbon migration and isomerization of 4,4-biaryl-substituted 1-butenes, in which the (EtO)3SiH plays a key role in the palladium-catalyzed one-carbon migration and subsequent isomerization of terminal alkenes. This catalytic protocol is applied in the synthesis of a key building block of cassumunin C in high yield and promising selectivity. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Founder of China (NSFC) (Grant No. 21173064);the Zhejiang Provincial Natural Science Foundation of China (ZPNSFC, Q12B020037);the Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT, JTAS 2011-01-014) |
| 语种 | 英语 |
| WOS记录号 | WOS:000331220800021 |
| 源URL | [http://210.77.64.217/handle/362003/18308]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Univ Chinese Acad Sci, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bai XF,Song, Tao,Deng WH,et al. (EtO)(3)SiH-Promoted Palladium-Catalyzed Isomerization of Olefins: Convenient Synthesis of Internal Alkenes from Terminal Alkenes[J]. SYNLETT,2014,25(3):417-422. |
| APA | Bai XF.,Song, Tao.,Deng WH.,Wei, Yun-Long.,Li L.,...&Xu LW.(2014).(EtO)(3)SiH-Promoted Palladium-Catalyzed Isomerization of Olefins: Convenient Synthesis of Internal Alkenes from Terminal Alkenes.SYNLETT,25(3),417-422. |
| MLA | Bai XF,et al."(EtO)(3)SiH-Promoted Palladium-Catalyzed Isomerization of Olefins: Convenient Synthesis of Internal Alkenes from Terminal Alkenes".SYNLETT 25.3(2014):417-422. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。