Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN
文献类型：期刊论文
| 作者 | Xie YJ(谢银君); Guo SM(郭生梅); Wu, Longmin; Xia CG(夏春谷) ; Huang HM(黄汉民)
|
| 刊名 | Angewandte Chemie International Edition
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:20页码:5900-5904 |
| 关键词 | AIBN cinnamic acids copper enolates single-electron transfer |
| ISSN号 | 1433-7851 |
| 通讯作者 | 黄汉民 |
| 英文摘要 | A new strategy for tuning the electron transfer between radicals and enolates has been developed. This method elicits the innate reactivity of AIBN with a copper catalyst and enables a cascade reaction with cinnamic acids. Electron paramagnetic resonance studies and control experiments indicate that the redox-active copper species not only activates the radical by coordination, but also serves as a bridge to bring the radical and nucleophile within close proximity to facilitate electron transfer. By exploiting possible combinations of redox-active metals and radical entities with suitable coordinating functional groups, this strategy should contribute to the development of a broad range of radical-based reactions. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21372231;21133011) |
| 语种 | 英语 |
| WOS记录号 | WOS:000354255400014 |
| 源URL | [http://210.77.64.217/handle/362003/18345]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie YJ,Guo SM,Wu, Longmin,et al. Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN[J]. Angewandte Chemie International Edition,2015,54(20):5900-5904. |
| APA | Xie YJ,Guo SM,Wu, Longmin,Xia CG,&Huang HM.(2015).Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN.Angewandte Chemie International Edition,54(20),5900-5904. |
| MLA | Xie YJ,et al."Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN".Angewandte Chemie International Edition 54.20(2015):5900-5904. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。