Copper-Catalyzed alpha-Benzylation of Enones via Radical-Triggered Oxidative Coupling of Two C-H Bonds
文献类型：期刊论文
| 作者 | Qin GP(秦贵平); Chen XN(陈向宁); Yang L(杨磊) ; Huang HM(黄汉民); Huang HM(黄汉民)
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| 刊名 | ACS Catalysis
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| 出版日期 | 2015 |
| 卷号 | 5期号:5页码:2882-2885 |
| 关键词 | oxidative coupling C-H activation radical copper catalysis benzylation enones regioselectivity |
| ISSN号 | 2155-5435 |
| 通讯作者 | 黄汉民 |
| 英文摘要 | A novel copper(II)-catalyzed, regioselective C–H benzylation of enones with toluenes via radical triggered oxidative coupling has been developed. A series of enones and toluenes with different substituents were successfully incorporated, providing a wide range of α-benzylated enones with TBP as oxidant by cleavage of C(sp3)–H bond and C(sp2)–H bond. Preliminary mechanistic study reveals a benzylic carbon radical is generated, and regioselectively reacts with enones to deliver the corresponding products. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21372231;21133011) |
| 语种 | 英语 |
| WOS记录号 | WOS:000354012200025 |
| 源URL | [http://210.77.64.217/handle/362003/18439]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Huang HM(黄汉民) |
| 作者单位 | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin GP,Chen XN,Yang L,et al. Copper-Catalyzed alpha-Benzylation of Enones via Radical-Triggered Oxidative Coupling of Two C-H Bonds[J]. ACS Catalysis,2015,5(5):2882-2885. |
| APA | Qin GP,Chen XN,Yang L,Huang HM,&黄汉民.(2015).Copper-Catalyzed alpha-Benzylation of Enones via Radical-Triggered Oxidative Coupling of Two C-H Bonds.ACS Catalysis,5(5),2882-2885. |
| MLA | Qin GP,et al."Copper-Catalyzed alpha-Benzylation of Enones via Radical-Triggered Oxidative Coupling of Two C-H Bonds".ACS Catalysis 5.5(2015):2882-2885. |
入库方式： OAI收割
来源：兰州化学物理研究所
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