Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway
文献类型：期刊论文
| 作者 | Shen ZL(沈振陆)1; Chen, Meng1; Fang, Tiantian2; Li, Meichao1; Mo WM(莫卫民)1; Hu BX(胡宝祥)1; Sun N(孙楠)1; Hu XQ(胡信全)1,3 |
| 刊名 | Tetrahedron Letters
 |
| 出版日期 | 2015 |
| 卷号 | 56期号:21页码:2768-2772 |
| 关键词 | Functional group interconversion PMB ethers Carbonyl compounds Oxidation Oxygen |
| ISSN号 | 0040-4039 |
| 通讯作者 | 沈振陆 ; 胡信全 |
| 英文摘要 | A facile and efficient protocol for direct transformation of p-methoxybenzyl (PMB) ethers to aldehydes or ketones via a catalytic aerobic oxidation process has been developed. The reaction was performed with the combination of catalytic amounts of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 2,2,6,6-tetramethylpiperidine N-oxy (TEMPO), and tert-butyl nitrite (TBN), with molecular oxygen as terminal oxidant. A variety of PMB ether substrates derived from benzylic alcohols, heteroaromatic alcohols, and aliphatic alcohols, were converted to their corresponding carbonyl compounds in good conversions and selectivities. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (21376224;21206147);Opening Foundation of Zhejiang Key Course of Chemical Engineering and Technology, Zhejiang University of Technology (20130211) |
| 语种 | 英语 |
| WOS记录号 | WOS:000355036400030 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://210.77.64.217/handle/362003/18444]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 2.Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen ZL,Chen, Meng,Fang, Tiantian,et al. Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway[J]. Tetrahedron Letters,2015,56(21):2768-2772. |
| APA | Shen ZL.,Chen, Meng.,Fang, Tiantian.,Li, Meichao.,Mo WM.,...&Hu XQ.(2015).Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway.Tetrahedron Letters,56(21),2768-2772. |
| MLA | Shen ZL,et al."Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway".Tetrahedron Letters 56.21(2015):2768-2772. |
入库方式： OAI收割
来源：兰州化学物理研究所
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